Information card for entry 4512515

Structure parameters

• Formula: C19 H22 Co N3 Si
• Calculated formula: C19 H22 Co N3 Si
• SMILES: c1cccc2c3cccc4c5cccc[n]5[Co](C[Si](C)(C)C)([n]12)[n]34
• Title of publication: High-Activity Cobalt Catalysts for Alkene Hydroboration with Electronically Responsive Terpyridine and α-Diimine Ligands
• Authors of publication: Palmer, W. Neil; Diao, Tianning; Pappas, Iraklis; Chirik, Paul J.
• Journal of publication: ACS Catalysis
• Year of publication: 2015
• Journal volume: 5
• Journal issue: 2
• Pages of publication: 622
• a: 11.086 ± 0.005 Å
• b: 19.096 ± 0.005 Å
• c: 16.774 ± 0.005 Å
• α: 90°
• β: 94.52 ± 0.005°
• γ: 90°
• Cell volume: 3540 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1014
• Residual factor for significantly intense reflections: 0.0698
• Weighted residual factors for significantly intense reflections: 0.1698
• Weighted residual factors for all reflections included in the refinement: 0.1918
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No