Information card for entry 4513826

Structure parameters

• Chemical name: cis-(ITMe)2Pd(SiMe2Ph)2
• Formula: C33 H49 N4 Pd Si2
• Calculated formula: C33 H49 N4 Pd Si2
• Title of publication: (N-Heterocyclic Carbene)2-Pd(0)-Catalyzed Silaboration of Internal and Terminal Alkynes: Scope and Mechanistic Studies
• Authors of publication: Ansell, Melvyn B.; Spencer, John; Navarro, Oscar
• Journal of publication: ACS Catalysis
• Year of publication: 2016
• Journal volume: 6
• Journal issue: 4
• Pages of publication: 2192
• a: 11.8802 ± 0.0006 Å
• b: 12.1897 ± 0.0005 Å
• c: 13.9679 ± 0.0005 Å
• α: 86.341 ± 0.003°
• β: 73.708 ± 0.004°
• γ: 63.295 ± 0.005°
• Cell volume: 1729.87 ± 0.16 ų
• Cell temperature: 173.15 K
• Ambient diffraction temperature: 173.15 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.044
• Residual factor for significantly intense reflections: 0.0396
• Weighted residual factors for significantly intense reflections: 0.1101
• Weighted residual factors for all reflections included in the refinement: 0.1171
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9017
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No