Information card for entry 4514737

Structure parameters

• Formula: C89 H64 Al B2 F36 N O6 P4 Rh2
• Calculated formula: C89 H64 Al B2 F36 N O6 P4 Rh2
• Title of publication: Dehydropolymerization of H₃B·NMeH₂ Using a [Rh(DPEphos)]⁺ Catalyst: The Promoting Effect of NMeH₂.
• Authors of publication: Adams, Gemma M.; Ryan, David E.; Beattie, Nicholas A.; McKay, Alasdair I.; Lloyd-Jones, Guy C; Weller, Andrew S.
• Journal of publication: ACS catalysis
• Year of publication: 2019
• Journal volume: 9
• Journal issue: 4
• Pages of publication: 3657 - 3666
• a: 14.5138 ± 0.0002 Å
• b: 18.5644 ± 0.0003 Å
• c: 21.462 ± 0.0003 Å
• α: 104.385 ± 0.001°
• β: 102.683 ± 0.001°
• γ: 107.545 ± 0.001°
• Cell volume: 5062.15 ± 0.14 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0717
• Residual factor for significantly intense reflections: 0.0579
• Weighted residual factors for significantly intense reflections: 0.1577
• Weighted residual factors for all reflections included in the refinement: 0.173
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No