Information card for entry 4515422

Structure parameters

• Common name: Co-POM
• Formula: Co4 K6 Na4 O94 P2 W18
• Calculated formula: Co4 K6 Na4 O94 P2 W18
• SMILES: [K+].O.O.[K+].O.O.O.[K+].O.[O]12P3(=O)[O]4[W]567(O[W]89(O3)(O[W]3%10(O[W]%11%122(O[W]2%131([O]1[Co]%14%15([O]=[W]%16%17(O[W]%18%19(OP%20(=O)[O]%21[W]%22%23%24([O]%25[Co]([O]=3)([O]=9)([O]3[W]9%26([O]%20[W](O%19)(=[O][Co]13[O]%12)(=O)(O[W]1(O[W](O%24)(O[W]%21(O%22)(=O)(=[O][Co]%25([O]=5)[O]%15[W]4(O%13)(O[W]3(O[W](O2)(O%11)(=O)O[W](O%10)(O3)(=O)O8)(O6)=O)(O7)=O)O%16)(O[W](O%17)(O1)(=O)O%18)=O)(=O)O9)O%26)(O%23)=O)[OH2])=O)(=[O]%14)=O)=O)[OH2])=O)=O)=O)=O)=O.[Na+].O.O.[Na+].O.O.O.O.[K+].O.O.[K+].O.O.O.[K+].O.[Na+].O.O.[Na+].O.O.O.O
• Title of publication: Stabilization of Cobalt-Polyoxometalate over Poly(ionic liquid) Composites for Efficient Electrocatalytic Water Oxidation.
• Authors of publication: Adhikary, Subhasis D.; Tiwari, Aarti; Nagaiah, Tharamani C.; Mandal, Debaprasad
• Journal of publication: ACS applied materials & interfaces
• Year of publication: 2018
• Journal volume: 10
• Journal issue: 45
• Pages of publication: 38872 - 38879
• a: 11.871 ± 0.0009 Å
• b: 16.6766 ± 0.0014 Å
• c: 21.2198 ± 0.0018 Å
• α: 90°
• β: 100.389 ± 0.003°
• γ: 90°
• Cell volume: 4132 ± 0.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0466
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for significantly intense reflections: 0.1017
• Weighted residual factors for all reflections included in the refinement: 0.105
• Goodness-of-fit parameter for all reflections included in the refinement: 1.083
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No