Information card for entry 4515687

Structure parameters

• Chemical name: GON-GC-332
• Formula: C85 H148 Au4 Cl4 F24 N4 O10 P4 S2 Sb4
• Calculated formula: C85 H148 Au4 Cl4 F24 N4 O10 P4 S2 Sb4
• Title of publication: TADDOL-Derived Cationic Phosphonites: Toward an Effective Enantioselective Synthesis of [6]Helicenes via Au-Catalyzed Alkyne Hydroarylation
• Authors of publication: Nicholls, Leo D. M.; Marx, Maximilian; Hartung, Thierry; González-Fernández, Elisa; Golz, Christopher; Alcarazo, Manuel
• Journal of publication: ACS Catalysis
• Year of publication: 2018
• Journal volume: 8
• Journal issue: 7
• Pages of publication: 6079
• a: 14.1224 ± 0.0013 Å
• b: 14.3201 ± 0.0006 Å
• c: 16.3265 ± 0.0014 Å
• α: 111.05 ± 0.006°
• β: 108.05 ± 0.008°
• γ: 90.835 ± 0.005°
• Cell volume: 2900.2 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 10
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0359
• Residual factor for significantly intense reflections: 0.0301
• Weighted residual factors for significantly intense reflections: 0.1143
• Weighted residual factors for all reflections included in the refinement: 0.1211
• Goodness-of-fit parameter for all reflections included in the refinement: 0.97
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No