Information card for entry 4517808

Structure parameters

• Chemical name: Rh(DPEphos)(CH2Ph)
• Formula: C43 H35 O P2 Rh
• Calculated formula: C43 H35 O P2 Rh
• Title of publication: Amine‒Borane Dehydropolymerization Using Rh-Based Precatalysts: Resting State, Chain Control, and Efficient Polymer Synthesis
• Authors of publication: Ryan, David E.; Andrea, Kori A.; Race, James J.; Boyd, Timothy M.; Lloyd-Jones, Guy C.; Weller, Andrew S.
• Journal of publication: ACS Catalysis
• Year of publication: 2020
• Pages of publication: 7443 - 7448
• a: 11.1012 ± 0.0004 Å
• b: 11.5775 ± 0.0005 Å
• c: 13.3634 ± 0.0004 Å
• α: 89.848 ± 0.003°
• β: 77.424 ± 0.003°
• γ: 78.168 ± 0.003°
• Cell volume: 1639.11 ± 0.11 ų
• Cell temperature: 150.01 ± 0.14 K
• Ambient diffraction temperature: 150.01 ± 0.14 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.042
• Residual factor for significantly intense reflections: 0.0358
• Weighted residual factors for significantly intense reflections: 0.0861
• Weighted residual factors for all reflections included in the refinement: 0.0911
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No