Preparation and Characterization of 1,3-Butadiene and Isoprene Complexes, W~2~(OCH~2~^t^Bu)~6~(diene)(py), and Studies of the Selective Hydrogenation of 1,3-Dienes
Authors of publication
Barry, Jane T.; Bollinger, John C.; Chisholm, Malcolm H.; Glasgow, Katherine C.; Huffman, John C.; Lucas, Eric A.; Lubkovsky, Emil B.; Streib, William E.
Journal of publication
Organometallics
Year of publication
1999
Journal volume
18
Journal issue
12
Pages of publication
2300 - 2308
a
10.52 ± 0.003 Å
b
18.475 ± 0.005 Å
c
26.692 ± 0.007 Å
α
90°
β
98.13 ± 0.015°
γ
90°
Cell volume
5135.5 ± 2.4 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0908
Residual factor for significantly intense reflections
0.0471
Weighted residual factors for all reflections
0.1145
Weighted residual factors for significantly intense reflections
0.0945
Goodness-of-fit parameter for all reflections
1.071
Goodness-of-fit parameter for significantly intense reflections
