Reactions of [(CO)~3~(P-P)Mn]~2~ with primary alcohols, where, P-P is dppe {Ph~2~P(CH~2~)~2~PPh~2~}, dppp {Ph~2~P(CH~2~)~3~PPh~2~}, dppb {Ph~2~P(CH~2~)~4~PPh~2~}, dpppe {Ph~2~P(CH~2~)~5~PPh~2~}, dtpe {(p-tol)~2~P(CH~2~)~2~P(p-tol)~2~}, or dcpe {(^c^hex)~2~P(CH~2~)~2~P(^c^hex)~2~}. Synthesis of fac-(CO)~3~(P-P)MnH and the X-ray structure of fac-(CO)~3~(dtpe)MnH
Authors of publication
O'Keiffe, L. S.; Mitchell, A. C.; Becker, T. M.; Ho, D. M.; Mandal, S. K.
Journal of publication
Journal of Organometallic Chemistry
Year of publication
2000
Journal volume
613
Journal issue
1
Pages of publication
13
a
14.0352 ± 0.0004 Å
b
10.8625 ± 0.0003 Å
c
19.6268 ± 0.0006 Å
α
90°
β
90°
γ
90°
Cell volume
2992.25 Å3
Ambient diffraction temperature
200 K
Number of distinct elements
5
Space group number
33
Hermann-Mauguin space group symbol
P n a 21
Hall space group symbol
P 2c -2n
Residual factor for significantly intense reflections
3.92
Weighted residual factors for significantly intense reflections
