Information card for entry 7001351

Structure parameters

• Formula: C35 H42 Cl2 N4 O2 P2 Rh2
• Calculated formula: C35 H42 Cl2 N4 O2 P2 Rh2
• SMILES: [Rh]1(Cl)([P@@](C[P@@]2([Rh](Cl)([N](c3c2cccc3)(C)C)C#[O])c2c(N(C)C)cccc2)(c2c([N]1(C)C)cccc2)c1c(N(C)C)cccc1)C#[O].[Rh]1(Cl)([P@](C[P@]2([Rh](Cl)([N](c3c2cccc3)(C)C)C#[O])c2c(N(C)C)cccc2)(c2c([N]1(C)C)cccc2)c1c(N(C)C)cccc1)C#[O]
• Title of publication: Mono- and binuclear complexes of rhodium involving a new series of hemilabile o-phosphinoaniline ligands
• Authors of publication: Hounjet, Lindsay J.; Bierenstiel, Matthias; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 21
• Pages of publication: 4213 - 4226
• a: 17.363 ± 0.003 Å
• b: 20.18 ± 0.003 Å
• c: 20.91 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7327 ± 2 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0578
• Residual factor for significantly intense reflections: 0.0424
• Weighted residual factors for significantly intense reflections: 0.091
• Weighted residual factors for all reflections included in the refinement: 0.098
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No