Information card for entry 7001667

Structure parameters

• Common name: Dichloro(mu-(1,3-di-tert-butyl-N,N,N',N-tetraethyl- (1,3,2,4)diazadiphosphetidine-2,4-diamine)digold(i)
• Chemical name: Dichloro(μ-(1,3-di-tert-butyl-N,N,N',N-tetraethyl- [1,3,2,4]diazadiphosphetidine-2,4-diamine)digold(I)
• Formula: C16 H38 Au2 Cl2 N4 P2
• Calculated formula: C16 H38 Au2 Cl2 N4 P2
• SMILES: [Au](Cl)[P]1(N(C(C)(C)C)[P]([Au]Cl)(N1C(C)(C)C)N(CC)CC)N(CC)CC
• Title of publication: Gold(i) complexes of cyclodiphosphazanes cis-{RP(μ-NtBu)}2: structure of a novel tetranuclear gold(i) macrocycle, [{Au{(o-MeOC6H4O)P(μ-NtBu)}2}4](ClO4)4
• Authors of publication: Chandrasekaran, P.; Mague, Joel T.; Balakrishna, Maravanji S.
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 28
• Pages of publication: 5478 - 5486
• a: 16.954 ± 0.001 Å
• b: 16.68 ± 0.001 Å
• c: 17.748 ± 0.001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5019 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0217
• Residual factor for significantly intense reflections: 0.0187
• Weighted residual factors for significantly intense reflections: 0.0418
• Weighted residual factors for all reflections included in the refinement: 0.0427
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No