Information card for entry 7001671

Structure parameters

• Common name: cyclo-tetra(mu-1,3-di-tert-butyl-2,4-bis(o-methoxyphenoxy) (1,3,2,4)diazadiphpsphetidine-1kappaP:2kappaP')tetragold(i) perchlorate hydrate
• Chemical name: cyclo-tetra(μ-1,3-di-tert-butyl-2,4-bis(o-methoxyphenoxy) [1,3,2,4]diazadiphpsphetidine-1κP:2κP')tetragold(I) perchlorate hydrate
• Formula: C88 H128 Au4 Cl4 N8 O34.5 P8
• Calculated formula: C88 H128 Au4 Cl4 N8 O34.5 P8
• Title of publication: Gold(i) complexes of cyclodiphosphazanes cis-{RP(μ-NtBu)}2: structure of a novel tetranuclear gold(i) macrocycle, [{Au{(o-MeOC6H4O)P(μ-NtBu)}2}4](ClO4)4
• Authors of publication: Chandrasekaran, P.; Mague, Joel T.; Balakrishna, Maravanji S.
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 28
• Pages of publication: 5478 - 5486
• a: 15.963 ± 0.002 Å
• b: 23.774 ± 0.002 Å
• c: 33.14 ± 0.003 Å
• α: 90°
• β: 107.852 ± 0.001°
• γ: 90°
• Cell volume: 11971 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0506
• Residual factor for significantly intense reflections: 0.0366
• Weighted residual factors for significantly intense reflections: 0.0873
• Weighted residual factors for all reflections included in the refinement: 0.0927
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No