Information card for entry 7001743

Structure parameters

• Common name: (C5H4Me)2Ti2(PhC(NSiMe3)2)2(u-O)2
• Chemical name: (C5H4Me)2Ti2{PhC(NSiMe3)2}2(u-O)2
• Formula: C25 H36 N2 O Si2 Ti
• Calculated formula: C25 H36 N2 O Si2 Ti
• Title of publication: Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion vs. cycloaddition-insertion
• Authors of publication: Guiducci, Aldo E.; Boyd, Catherine L.; Clot, Eric; Mountford, Philip
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 30
• Pages of publication: 5960 - 5979
• a: 10.132 ± 0.0004 Å
• b: 10.421 ± 0.0007 Å
• c: 15.31 ± 0.0011 Å
• α: 92.248 ± 0.004°
• β: 104.045 ± 0.005°
• γ: 118.207 ± 0.004°
• Cell volume: 1359.37 ± 0.16 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0694
• Weighted residual factors for all reflections included in the refinement: 0.0432
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0253
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No