Information card for entry 7002006

Structure parameters

• Formula: C18 H27 Br2 N4 Rh
• Calculated formula: C18 H27 Br2 N4 Rh
• SMILES: [Rh]123(Br)([CH]4=[CH]1CC[CH]2=[CH]3CC4)=C1N(C=CN1C)CCn1c[n+](cc1)C.[Br-]
• Title of publication: Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes
• Authors of publication: Zamora, Matthew T.; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 35
• Pages of publication: 7269
• a: 23.748 ± 0.002 Å
• b: 6.9405 ± 0.0007 Å
• c: 12.3794 ± 0.0012 Å
• α: 90°
• β: 91.48 ± 0.001°
• γ: 90°
• Cell volume: 2039.7 ± 0.3 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0463
• Residual factor for significantly intense reflections: 0.0314
• Weighted residual factors for significantly intense reflections: 0.0697
• Weighted residual factors for all reflections included in the refinement: 0.0753
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No