Reactions of palladium and gold complexes with zinc-thiolate chelates using electrospray mass spectrometry and X-ray diffraction: molecular identification of [Pd(bme-dach)], [Au(bme-dach]+ and [ZnCl(bme-dach)]2Pd
Authors of publication
de Paula, Queite A.; Liu, Qin; Almaraz, Elky; Denny, Jason A.; Mangrum, John B.; Bhuvanesh, Nattamai; Darensbourg, Marcetta Y.; Farrell, Nicholas P.
Journal of publication
Dalton Transactions
Year of publication
2009
Journal issue
48
Pages of publication
10896 - 10903
a
7.4293 ± 0.0002 Å
b
12.4008 ± 0.0004 Å
c
16.6452 ± 0.0006 Å
α
90°
β
97.128 ± 0.002°
γ
90°
Cell volume
1521.66 ± 0.08 Å3
Cell temperature
110 ± 2 K
Ambient diffraction temperature
110 ± 2 K
Number of distinct elements
7
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0349
Residual factor for significantly intense reflections
0.0295
Weighted residual factors for significantly intense reflections
0.0769
Weighted residual factors for all reflections included in the refinement
0.0799
Goodness-of-fit parameter for all reflections included in the refinement
