Information card for entry 7003687

Structure parameters

• Formula: C44 H57 P4 Rh
• Calculated formula: C44 H57 P4 Rh
• SMILES: c1(c(cc(cc1C)C)C)[PH]1P(c2c(cc(cc2C)C)C)P(c2c(cc(cc2C)C)C)P(c2c(cc(cc2C)C)C)[Rh]2341[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Different transmetallation behaviour of [M(P4HR4)] salts toward rhodium(i) and copper(i) (M = Na, K; R = Ph, Mes; Mes = 2,4,6-Me3C6H2)
• Authors of publication: Gómez-Ruiz, Santiago; Wolf, Robert; Hey-Hawkins, Evamarie
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 15
• Pages of publication: 1982 - 1988
• a: 8.225 ± 0.0014 Å
• b: 11.9022 ± 0.0017 Å
• c: 21.536 ± 0.004 Å
• α: 105.206 ± 0.014°
• β: 94.195 ± 0.014°
• γ: 92.753 ± 0.013°
• Cell volume: 2024.1 ± 0.6 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0823
• Residual factor for significantly intense reflections: 0.043
• Weighted residual factors for significantly intense reflections: 0.0731
• Weighted residual factors for all reflections included in the refinement: 0.0843
• Goodness-of-fit parameter for all reflections included in the refinement: 0.994
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No