Information card for entry 7003992

Structure parameters

• Formula: C19 H27 Cl2 N4 Rh S2
• Calculated formula: C19 H27 Cl2 N4 Rh S2
• Title of publication: Syntheses and structures of half-sandwich iridium(iii) and rhodium(iii) complexes with organochalcogen (S, Se) ligands bearing N-methylimidazole and their use as catalysts for norbornene polymerization
• Authors of publication: Jia, Wei-Guo; Huang, Yuan-Biao; Lin, Yue-Jian; Jin, Guo-Xin
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 41
• Pages of publication: 5612 - 5620
• a: 10.21 ± 0.004 Å
• b: 11.469 ± 0.004 Å
• c: 22.139 ± 0.009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2592.4 ± 1.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.0595
• Residual factor for significantly intense reflections: 0.0417
• Weighted residual factors for significantly intense reflections: 0.0845
• Weighted residual factors for all reflections included in the refinement: 0.0899
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No