Information card for entry 7004374

Structure parameters

• Common name: (cyclopentadienyl)(triisopropylphosphine)(dimethylchlorosilyl) ruthenium dihydride
• Chemical name: (cyclopentadienyl)(triisopropylphosphine)(dimethylchlorosilyl) ruthenium dihydride
• Formula: C16 H34 Cl P Ru Si
• Calculated formula: C16 H34 Cl P Ru Si
• Title of publication: Unexpected effect of the ring on the extent of Si⋯H interligand interactions in half-sandwich silyl hydrides of ruthenium
• Authors of publication: Gutsulyak, Dmitry V.; Osipov, Alexandr L.; Kuzmina, Lyudmila G.; Howard, Judith A. K.; Nikonov, Georgii I.
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 47
• Pages of publication: 6843 - 6850
• a: 9.4433 ± 0.0002 Å
• b: 15.4953 ± 0.0004 Å
• c: 13.8057 ± 0.0004 Å
• α: 90°
• β: 94.167 ± 0.001°
• γ: 90°
• Cell volume: 2014.8 ± 0.09 ų
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0624
• Weighted residual factors for all reflections included in the refinement: 0.0653
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No