Information card for entry 7004431

Structure parameters

• Common name: [Au{C(NHCH3)(NHCH2CH2OH)}2]3(AsF6)2Cl.0.5(H2O)2
• Formula: C24 H62 As2 Au3 Cl F12 N12 O7
• Calculated formula: C24 H60 As2 Au3 Cl F12 N12 O7
• Title of publication: Colorless, non-luminescent; colorless, luminescent; and yellow, luminescent crystals of the cation [Au{C(NHCH3)(NHCH2CH2OH)}2]+. The roles of anions and hydrogen bonding in determining the aggregation of two-coordinate gold(i) cations
• Authors of publication: Rios, Daniel; Olmstead, Marilyn M.; Balch, Alan L.
• Journal of publication: Dalton Transactions
• Year of publication: 2008
• Journal issue: 31
• Pages of publication: 4157 - 4164
• a: 9.4814 ± 0.0005 Å
• b: 20.7388 ± 0.001 Å
• c: 24.6413 ± 0.0012 Å
• α: 90°
• β: 90.965 ± 0.001°
• γ: 90°
• Cell volume: 4844.6 ± 0.4 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0722
• Residual factor for significantly intense reflections: 0.0355
• Weighted residual factors for significantly intense reflections: 0.0758
• Weighted residual factors for all reflections included in the refinement: 0.0846
• Goodness-of-fit parameter for all reflections included in the refinement: 0.995
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No