Information card for entry 7004856

Structure parameters

• Common name: Bis(1,2-diaminoethane)((3- aminopropyl)dimethylphosphine)cobalt(iii) Dichloride Hexafluorophosphate
• Chemical name: Bis(1,2-diaminoethane)((3-aminopropyl)dimethylphosphine)cobalt(III) Dichloride Hexafluorophosphate
• Formula: C9 H30 Cl2 Co F6 N5 P2
• Calculated formula: C9 H30 Cl2 Co F6 N5 P2
• SMILES: [Co]123([P](C)(C)CCC[NH2]1)([NH2]CC[NH2]2)[NH2]CC[NH2]3.[Cl-].[Cl-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Preparation and characterization of mixed-ligand cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp). Conformation of the six-membered pdmp chelate ring.
• Authors of publication: Suzuki, Takayoshi; Fujiiwara, Katsuhiro; Takagi, Hideo D.; Kashiwabara, Kazuo
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 3
• Pages of publication: 308 - 319
• a: 10.6831 ± 0.0013 Å
• b: 12.793 ± 0.003 Å
• c: 7.807 ± 0.002 Å
• α: 107.309 ± 0.019°
• β: 96.862 ± 0.017°
• γ: 88.801 ± 0.016°
• Cell volume: 1011.2 ± 0.4 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0634
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.1241
• Weighted residual factors for all reflections included in the refinement: 0.135
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No