Molecular and electronic structure of square planar complexes [PdII(tbpy)(L N,O IP)]0, [PdII(tbpy)(LN,O ISQ)](PF6), and [PdII(tbpy)(L N,O IBQ)](PF6)(BF4).2CH2Cl2: an o-iminophenolato based ligand centered, three-membered redox series.
Authors of publication
Kokatam, Swarna-Latha; Chaudhuri, Phalguni; Weyhermüller, Thomas; Wieghardt, Karl
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2007
Journal issue
3
Pages of publication
373 - 378
a
37.901 ± 0.002 Å
b
11.5338 ± 0.0006 Å
c
26.74 ± 0.002 Å
α
90°
β
124.352 ± 0.006°
γ
90°
Cell volume
9650.4 ± 1.2 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
9
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0791
Residual factor for significantly intense reflections
0.0536
Weighted residual factors for significantly intense reflections
0.1201
Weighted residual factors for all reflections included in the refinement
0.1329
Goodness-of-fit parameter for all reflections included in the refinement
