Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2,a]pyrimidine).
Authors of publication
Brinkmann, Christine; García, Felipe; Morey, James V.; McPartlin, Mary; Singh, Sanjay; Wheatley, Andrew E. H.; Wright, Dominic S.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2007
Journal issue
16
Pages of publication
1570 - 1572
a
14.668 ± 0.003 Å
b
18.026 ± 0.004 Å
c
18.697 ± 0.004 Å
α
90°
β
107.01 ± 0.03°
γ
90°
Cell volume
4727.3 ± 1.9 Å3
Cell temperature
180 ± 2 K
Ambient diffraction temperature
180 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0767
Residual factor for significantly intense reflections
0.0521
Weighted residual factors for significantly intense reflections
0.1064
Weighted residual factors for all reflections included in the refinement
0.1142
Goodness-of-fit parameter for all reflections included in the refinement
