Information card for entry 7005502

Structure parameters

• Common name: Hexacarbony-bis(9-pentyl-9-phosphabicyclo(3.3.1)nonane)- dicobalt
• Chemical name: Hexacarbony-bis(9-pentyl-9-phosphabicyclo[3.3.1]nonane)-dicobalt
• Formula: C32 H50 Co2 O6 P2
• Calculated formula: C32 H50 Co2 O6 P2
• Title of publication: Bicyclic phosphines as ligands for cobalt catalysed hydroformylation. Crystal structures of [Co(Phoban[3.3.1]-Q)(CO)(3)](2) (Q = C(2)H(5), C(5)H(11), C(3)H(6)NMe(2), C(6)H(11)).
• Authors of publication: Bungu, Peter N.; Otto, Stefanus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 27
• Pages of publication: 2876 - 2884
• a: 9.2166 ± 0.0018 Å
• b: 9.3388 ± 0.0019 Å
• c: 11.667 ± 0.002 Å
• α: 92.67 ± 0.03°
• β: 109.75 ± 0.03°
• γ: 109.15 ± 0.03°
• Cell volume: 878.7 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0671
• Residual factor for significantly intense reflections: 0.0396
• Weighted residual factors for significantly intense reflections: 0.0927
• Weighted residual factors for all reflections included in the refinement: 0.1048
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No