Information card for entry 7005570

Structure parameters

• Formula: C32 H25 F6 N5 P Rh
• Calculated formula: C32 H25 F6 N5 P Rh
• SMILES: [Rh]123([n]4ccccc4Nc4[n]1cccc4)([n]1ccccc1c1ccccc21)[n]1ccccc1c1ccccc31.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Photophysical and electrochemical properties of new ortho-metalated complexes of rhodium(III) containing 2,2'-dipyridylketone and 2,2'-dipyridylamine. An experimental and theoretical study.
• Authors of publication: Su, Wei Lin; Yu, Yu Cheng; Tseng, Mei Ching; Wang, Shao Pin; Huang, Wen Liang
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 31
• Pages of publication: 3440 - 3449
• a: 11.1828 ± 0.0002 Å
• b: 16.6037 ± 0.0004 Å
• c: 31.8082 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5906 ± 0.2 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0658
• Residual factor for significantly intense reflections: 0.0389
• Weighted residual factors for significantly intense reflections: 0.0998
• Weighted residual factors for all reflections included in the refinement: 0.1281
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No