Information card for entry 7006386

Structure parameters

• Common name: bis-((mu2-bicyclo(2.2.1)heptane-2-one oximato-N,O) dimethylaluminium)
• Chemical name: bis-({μ2-bicyclo[2.2.1]heptane-2-one oximato-N,O} dimethylaluminium)
• Formula: C18 H32 Al2 N2 O2
• Calculated formula: C18 H32 Al2 N2 O2
• SMILES: C[Al]1(C)O[N](=C2[C@@H]3C[C@@H](CC3)C2)[Al](C)(C)O[N]1=C1[C@H]2C[C@H](CC2)C1
• Title of publication: Organoaluminium complexes with sterically demanding oximato ligands: does a bulky and rigid ligand backbone change the aggregation motif?
• Authors of publication: Ullrich, Matthias; Mitzel, Norbert W.; Bergander, Klaus; Fröhlich, Roland
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 5
• Pages of publication: 714 - 721
• a: 19.235 ± 0.004 Å
• b: 8.384 ± 0.0017 Å
• c: 12.596 ± 0.003 Å
• α: 90°
• β: 90.19 ± 0.03°
• γ: 90°
• Cell volume: 2031.3 ± 0.8 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 1 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0518
• Residual factor for significantly intense reflections: 0.0424
• Weighted residual factors for significantly intense reflections: 0.1153
• Weighted residual factors for all reflections included in the refinement: 0.1215
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71093 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No