#------------------------------------------------------------------------------
#$Date: 2025-08-21 12:25:49 +0200 (Thu 21 de Aug de 2025) $
#$Revision: 301846 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/67/7006768.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7006768
loop_
_publ_author_name
'Jiménez-Rodríguez, Cristina'
'Roca, Francesc X.'
'Bo, Carles'
'Benet-Buchholz, Jordi'
'Escudero-Adán, Eduardo C'
'Freixa, Zoraida'
'van Leeuwen, Piet W. N. M.'
_publ_section_title
;
 SPANphos: trans-spanning diphosphines as cis chelating ligands!
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              268
_journal_page_last               278
_journal_paper_doi               10.1039/b513870c
_journal_year                    2006
_chemical_formula_sum            'C56 H80 B Cl6 F4 O2 P2 Rh'
_chemical_formula_weight         1249.56
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.4700(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.4171(6)
_cell_length_b                   27.9184(14)
_cell_length_c                   17.4627(9)
_cell_measurement_reflns_used    8292
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      39.18
_cell_measurement_theta_min      2.73
_cell_volume                     5861.7(5)
_computing_cell_refinement       'Bruker-Nonius Apex v1.0-22 2002'
_computing_data_collection       'Bruker-Nonius Apex v1.0-22 2002'
_computing_data_reduction        'SAINT+ Version 7.06A Bruker-Nonius, 2004'
_computing_molecular_graphics    'Shelxtl Version 6.12 (Sheldrick, 2001)'
_computing_publication_material  'Shelxtl Version 6.12 (Sheldrick, 2001)'
_computing_structure_refinement  'Shelxtl Version 6.12 (Sheldrick, 2001)'
_computing_structure_solution    'Shelxtl Version 6.12 (Sheldrick, 2001)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 512
_diffrn_detector_type            '4K CCD area detector APEX II'
_diffrn_measured_fraction_theta_full 0.852
_diffrn_measured_fraction_theta_max 0.852
_diffrn_measurement_device_type  'Kappa 4-axis goniometer bruker-nonius'
_diffrn_measurement_method
;
Fullsphere data collection, phi and omega scans
;
_diffrn_measurement_specimen_support
'magnetic support whith 10 micron nylon fiber cryoloop'
_diffrn_radiation_monochromator  'Multilayer Montel 200 mirrors'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0377
_diffrn_reflns_av_sigmaI/netI    0.0349
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       49
_diffrn_reflns_limit_k_min       -48
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            119031
_diffrn_reflns_theta_full        39.64
_diffrn_reflns_theta_max         39.64
_diffrn_reflns_theta_min         2.68
_diffrn_source                   'rotating anode X-ray tube'
_diffrn_source_current           90
_diffrn_source_power             50
_diffrn_source_size              '3 mm x 0.3 mm fine focus'
_diffrn_source_type              'Bruker-Nonius FR 591'
_exptl_absorpt_coefficient_mu    0.672
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6924
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
SADABS Version 2.1 2003 Bruker-Nonius
Blessing, Acta Cryst. (1995) A51 33-38
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.416
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2600
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.123
_refine_diff_density_min         -2.059
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     668
_refine_ls_number_reflns         30269
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_gt           0.0466
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0638P)²+6.1836P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1232
_refine_ls_wR_factor_ref         0.1342
_reflns_number_gt                24476
_reflns_number_total             30269
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b513870c.txt
_cod_data_source_block           cji40_0m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_diffrn_measurement_specimen_suppport' tag replaced with
'_diffrn_measurement_specimen_support'.

Automatic conversion script
Id: cif_correct_tags 1383 2010-08-28 14:59:44Z saulius 

The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7006768
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.732705(8) 0.167411(3) 0.252793(7) 0.01119(3) Uani 1 1 d . . .
P1 P 0.62642(3) 0.109877(12) 0.16456(2) 0.01113(6) Uani 1 1 d . . .
C1 C 0.75012(10) -0.03357(4) 0.24725(9) 0.0132(2) Uani 1 1 d . . .
O1 O 0.67003(8) -0.00354(3) 0.19536(7) 0.01351(17) Uani 1 1 d . . .
P2 P 0.84963(3) 0.111339(12) 0.33698(2) 0.01140(6) Uani 1 1 d . . .
C2 C 0.69812(11) -0.06482(5) 0.30081(10) 0.0158(2) Uani 1 1 d . . .
H2A H 0.7218 -0.0525 0.3556 0.019 Uiso 1 1 calc R . .
H2B H 0.7270 -0.0979 0.3008 0.019 Uiso 1 1 calc R . .
O2 O 0.82577(8) -0.00229(3) 0.30059(7) 0.01341(17) Uani 1 1 d . . .
C3 C 0.56981(12) -0.06629(5) 0.27543(10) 0.0167(2) Uani 1 1 d . . .
C4 C 0.53337(11) -0.01425(5) 0.26848(10) 0.0152(2) Uani 1 1 d . . .
C5 C 0.45159(12) 0.00501(5) 0.30080(11) 0.0188(3) Uani 1 1 d . . .
H5 H 0.4111 -0.0156 0.3268 0.023 Uiso 1 1 calc R . .
C6 C 0.42723(12) 0.05409(5) 0.29607(10) 0.0175(3) Uani 1 1 d . . .
C7 C 0.48571(11) 0.08339(5) 0.25631(10) 0.0153(2) Uani 1 1 d . . .
H7 H 0.4708 0.1168 0.2537 0.018 Uiso 1 1 calc R . .
C8 C 0.56656(10) 0.06531(4) 0.21958(9) 0.0125(2) Uani 1 1 d . . .
C9 C 0.59042(10) 0.01649(4) 0.22857(9) 0.0126(2) Uani 1 1 d . . .
C10 C 0.52804(14) -0.09215(6) 0.19562(12) 0.0236(3) Uani 1 1 d . . .
H10A H 0.4466 -0.0935 0.1819 0.035 Uiso 1 1 calc R . .
H10B H 0.5582 -0.1248 0.1997 0.035 Uiso 1 1 calc R . .
H10C H 0.5527 -0.0746 0.1545 0.035 Uiso 1 1 calc R . .
C11 C 0.52901(14) -0.09366(6) 0.33893(13) 0.0252(3) Uani 1 1 d . . .
H11A H 0.5528 -0.0768 0.3896 0.038 Uiso 1 1 calc R . .
H11B H 0.5605 -0.1260 0.3444 0.038 Uiso 1 1 calc R . .
H11C H 0.4476 -0.0957 0.3235 0.038 Uiso 1 1 calc R . .
C12 C 0.34197(14) 0.07427(7) 0.33576(12) 0.0241(3) Uani 1 1 d . . .
H12A H 0.3277 0.1079 0.3206 0.036 Uiso 1 1 calc R . .
H12B H 0.3702 0.0720 0.3933 0.036 Uiso 1 1 calc R . .
H12C H 0.2727 0.0560 0.3191 0.036 Uiso 1 1 calc R . .
C13 C 0.80724(12) -0.06130(5) 0.19246(10) 0.0162(2) Uani 1 1 d . . .
H13A H 0.7804 -0.0487 0.1380 0.019 Uiso 1 1 calc R . .
H13B H 0.7853 -0.0954 0.1918 0.019 Uiso 1 1 calc R . .
C14 C 0.93531(12) -0.05795(5) 0.21720(11) 0.0178(3) Uani 1 1 d . . .
C15 C 0.96100(11) -0.00479(5) 0.22469(10) 0.0152(2) Uani 1 1 d . . .
C16 C 1.03649(12) 0.01881(5) 0.19102(11) 0.0185(3) Uani 1 1 d . . .
H16 H 1.0789 0.0009 0.1627 0.022 Uiso 1 1 calc R . .
C17 C 1.05090(12) 0.06851(5) 0.19828(10) 0.0176(3) Uani 1 1 d . . .
C18 C 0.98986(11) 0.09386(5) 0.24144(10) 0.0153(2) Uani 1 1 d . . .
H18 H 0.9991 0.1276 0.2462 0.018 Uiso 1 1 calc R . .
C19 C 0.91443(10) 0.07120(4) 0.27845(9) 0.0123(2) Uani 1 1 d . . .
C20 C 0.89992(10) 0.02203(4) 0.26726(9) 0.0126(2) Uani 1 1 d . . .
C21 C 0.98050(15) -0.08245(6) 0.15311(14) 0.0271(4) Uani 1 1 d . . .
H21A H 0.9543 -0.0653 0.1030 0.041 Uiso 1 1 calc R . .
H21B H 0.9541 -0.1156 0.1467 0.041 Uiso 1 1 calc R . .
H21C H 1.0620 -0.0821 0.1687 0.041 Uiso 1 1 calc R . .
C22 C 0.98346(14) -0.08328(6) 0.29680(13) 0.0247(3) Uani 1 1 d . . .
H22A H 1.0647 -0.0803 0.3111 0.037 Uiso 1 1 calc R . .
H22B H 0.9628 -0.1172 0.2921 0.037 Uiso 1 1 calc R . .
H22C H 0.9535 -0.0684 0.3379 0.037 Uiso 1 1 calc R . .
C23 C 1.12881(14) 0.09416(7) 0.15798(12) 0.0251(3) Uani 1 1 d . . .
H23A H 1.0922 0.0984 0.1018 0.038 Uiso 1 1 calc R . .
H23B H 1.1966 0.0751 0.1633 0.038 Uiso 1 1 calc R . .
H23C H 1.1481 0.1256 0.1827 0.038 Uiso 1 1 calc R . .
C24 C 0.49373(11) 0.13422(4) 0.09995(9) 0.0133(2) Uani 1 1 d . . .
H24 H 0.4622 0.1551 0.1355 0.016 Uiso 1 1 calc R . .
C25 C 0.50989(11) 0.16766(5) 0.03358(9) 0.0141(2) Uani 1 1 d . . .
H25A H 0.5702 0.1908 0.0553 0.017 Uiso 1 1 calc R . .
H25B H 0.5317 0.1486 -0.0079 0.017 Uiso 1 1 calc R . .
C26 C 0.40193(12) 0.19475(5) -0.00248(10) 0.0167(2) Uani 1 1 d . . .
H26A H 0.3826 0.2152 0.0384 0.020 Uiso 1 1 calc R . .
H26B H 0.4129 0.2158 -0.0456 0.020 Uiso 1 1 calc R . .
C27 C 0.30669(12) 0.15993(6) -0.03522(11) 0.0189(3) Uani 1 1 d . . .
H27A H 0.3222 0.1420 -0.0803 0.023 Uiso 1 1 calc R . .
H27B H 0.2368 0.1781 -0.0549 0.023 Uiso 1 1 calc R . .
C28 C 0.29222(12) 0.12455(6) 0.02836(10) 0.0180(3) Uani 1 1 d . . .
H28A H 0.2335 0.1011 0.0046 0.022 Uiso 1 1 calc R . .
H28B H 0.2679 0.1421 0.0703 0.022 Uiso 1 1 calc R . .
C29 C 0.40068(11) 0.09781(5) 0.06507(10) 0.0159(2) Uani 1 1 d . . .
H29A H 0.4224 0.0781 0.0242 0.019 Uiso 1 1 calc R . .
H29B H 0.3896 0.0761 0.1073 0.019 Uiso 1 1 calc R . .
C30 C 0.70419(11) 0.08054(5) 0.09949(9) 0.0135(2) Uani 1 1 d . . .
H30 H 0.7591 0.0585 0.1339 0.016 Uiso 1 1 calc R . .
C31 C 0.63476(12) 0.04976(5) 0.03182(10) 0.0160(2) Uani 1 1 d . . .
H31A H 0.5948 0.0248 0.0540 0.019 Uiso 1 1 calc R . .
H31B H 0.5787 0.0702 -0.0039 0.019 Uiso 1 1 calc R . .
C32 C 0.70888(15) 0.02595(6) -0.01544(11) 0.0218(3) Uani 1 1 d . . .
H32A H 0.7599 0.0031 0.0190 0.026 Uiso 1 1 calc R . .
H32B H 0.6619 0.0077 -0.0601 0.026 Uiso 1 1 calc R . .
C33 C 0.77680(15) 0.06323(6) -0.04736(11) 0.0229(3) Uani 1 1 d . . .
H33A H 0.8267 0.0468 -0.0751 0.028 Uiso 1 1 calc R . .
H33B H 0.7260 0.0841 -0.0859 0.028 Uiso 1 1 calc R . .
C34 C 0.84576(13) 0.09368(6) 0.01956(11) 0.0200(3) Uani 1 1 d . . .
H34A H 0.8863 0.1184 -0.0028 0.024 Uiso 1 1 calc R . .
H34B H 0.9014 0.0732 0.0553 0.024 Uiso 1 1 calc R . .
C35 C 0.77263(12) 0.11810(5) 0.06693(10) 0.0161(2) Uani 1 1 d . . .
H35A H 0.7216 0.1410 0.0325 0.019 Uiso 1 1 calc R . .
H35B H 0.8201 0.1363 0.1114 0.019 Uiso 1 1 calc R . .
C36 C 0.97968(11) 0.13703(5) 0.40346(9) 0.0142(2) Uani 1 1 d . . .
H36 H 1.0082 0.1605 0.3699 0.017 Uiso 1 1 calc R . .
C37 C 1.07620(12) 0.10150(5) 0.43395(10) 0.0169(2) Uani 1 1 d . . .
H37A H 1.0559 0.0787 0.4715 0.020 Uiso 1 1 calc R . .
H37B H 1.0901 0.0830 0.3891 0.020 Uiso 1 1 calc R . .
C38 C 1.18172(12) 0.12889(6) 0.47536(11) 0.0199(3) Uani 1 1 d . . .
H38A H 1.2428 0.1059 0.4956 0.024 Uiso 1 1 calc R . .
H38B H 1.2044 0.1501 0.4368 0.024 Uiso 1 1 calc R . .
C39 C 1.16203(13) 0.15881(6) 0.54388(11) 0.0204(3) Uani 1 1 d . . .
H39A H 1.2302 0.1771 0.5683 0.025 Uiso 1 1 calc R . .
H39B H 1.1457 0.1373 0.5846 0.025 Uiso 1 1 calc R . .
C40 C 1.06507(13) 0.19352(5) 0.51533(10) 0.0188(3) Uani 1 1 d . . .
H40A H 1.0845 0.2171 0.4787 0.023 Uiso 1 1 calc R . .
H40B H 1.0513 0.2112 0.5611 0.023 Uiso 1 1 calc R . .
C41 C 0.95924(12) 0.16654(5) 0.47296(10) 0.0154(2) Uani 1 1 d . . .
H41A H 0.8985 0.1898 0.4530 0.018 Uiso 1 1 calc R . .
H41B H 0.9360 0.1449 0.5109 0.018 Uiso 1 1 calc R . .
C42 C 0.77585(11) 0.07713(5) 0.39943(9) 0.0140(2) Uani 1 1 d . . .
H42 H 0.7242 0.0548 0.3629 0.017 Uiso 1 1 calc R . .
C43 C 0.84722(12) 0.04571(5) 0.46503(10) 0.0170(2) Uani 1 1 d . . .
H43A H 0.8910 0.0229 0.4416 0.020 Uiso 1 1 calc R . .
H43B H 0.9000 0.0662 0.5031 0.020 Uiso 1 1 calc R . .
C44 C 0.77404(16) 0.01795(6) 0.50846(12) 0.0236(3) Uani 1 1 d . . .
H44A H 0.7263 -0.0047 0.4713 0.028 Uiso 1 1 calc R . .
H44B H 0.8219 -0.0009 0.5519 0.028 Uiso 1 1 calc R . .
C45 C 0.70088(17) 0.05172(7) 0.54238(12) 0.0272(4) Uani 1 1 d . . .
H45A H 0.7484 0.0722 0.5835 0.033 Uiso 1 1 calc R . .
H45B H 0.6517 0.0327 0.5675 0.033 Uiso 1 1 calc R . .
C46 C 0.63011(14) 0.08328(6) 0.47742(12) 0.0224(3) Uani 1 1 d . . .
H46A H 0.5769 0.0629 0.4395 0.027 Uiso 1 1 calc R . .
H46B H 0.5867 0.1060 0.5013 0.027 Uiso 1 1 calc R . .
C47 C 0.70142(12) 0.11130(5) 0.43313(10) 0.0168(2) Uani 1 1 d . . .
H47A H 0.7486 0.1344 0.4696 0.020 Uiso 1 1 calc R . .
H47B H 0.6526 0.1296 0.3894 0.020 Uiso 1 1 calc R . .
C48 C 0.71703(11) 0.22897(5) 0.17335(9) 0.0143(2) Uani 1 1 d . . .
H48 H 0.7124 0.2258 0.1156 0.017 Uiso 1 1 calc R . .
C49 C 0.62395(11) 0.22772(5) 0.20417(10) 0.0149(2) Uani 1 1 d . . .
H49 H 0.5465 0.2235 0.1706 0.018 Uiso 1 1 calc R . .
C50 C 0.65211(13) 0.25879(5) 0.27898(10) 0.0172(2) Uani 1 1 d . . .
H50 H 0.5887 0.2701 0.3001 0.021 Uiso 1 1 calc R . .
C51 C 0.74186(13) 0.22795(5) 0.33414(10) 0.0165(2) Uani 1 1 d . . .
H51 H 0.7469 0.2239 0.3918 0.020 Uiso 1 1 calc R . .
C52 C 0.83493(12) 0.22941(5) 0.30312(10) 0.0158(2) Uani 1 1 d . . .
H52 H 0.9128 0.2265 0.3365 0.019 Uiso 1 1 calc R . .
C53 C 0.80335(12) 0.26077(5) 0.22877(10) 0.0158(2) Uani 1 1 d . . .
H53 H 0.8655 0.2736 0.2078 0.019 Uiso 1 1 calc R . .
C54 C 0.72616(14) 0.29763(5) 0.25425(10) 0.0192(3) Uani 1 1 d . . .
H54A H 0.6850 0.3178 0.2099 0.023 Uiso 1 1 calc R . .
H54B H 0.7655 0.3179 0.2990 0.023 Uiso 1 1 calc R . .
Cl1B Cl 0.98466(6) 0.20338(2) -0.07517(5) 0.04507(15) Uani 1 1 d . . .
C1LB C 0.90160(18) 0.25153(8) -0.06044(18) 0.0371(5) Uani 1 1 d . . .
H1LA H 0.8288 0.2496 -0.1009 0.045 Uiso 1 1 calc R . .
Cl2B Cl 0.96561(7) 0.30593(2) -0.07317(6) 0.0594(2) Uani 1 1 d . . .
Cl3B Cl 0.87634(9) 0.24819(4) 0.03227(7) 0.0718(3) Uani 1 1 d . . .
C1LA C 0.23749(19) -0.23020(10) 0.32425(17) 0.0412(6) Uani 1 1 d . . .
H1LB H 0.2852 -0.2151 0.2925 0.049 Uiso 1 1 calc R A 1
Cl1A Cl 0.16877(10) -0.28216(3) 0.27343(8) 0.0460(2) Uani 0.864(3) 1 d P B 1
Cl1' Cl 0.2061(5) -0.28322(17) 0.3024(4) 0.0341(10) Uiso 0.136(3) 1 d P B 2
Cl2A Cl 0.13599(9) -0.19025(4) 0.33518(9) 0.0715(4) Uani 0.864(3) 1 d P B 1
Cl2' Cl 0.1353(13) -0.1884(5) 0.2696(10) 0.126(5) Uiso 0.136(3) 1 d P B 2
Cl3A Cl 0.32053(10) -0.24942(8) 0.41587(10) 0.1076(9) Uani 0.864(3) 1 d P B 1
Cl3' Cl 0.2932(8) -0.2185(4) 0.4266(6) 0.074(2) Uiso 0.136(3) 1 d P B 2
B1 B 0.3870(2) -0.21547(11) 0.1728(2) 0.0440(7) Uani 1 1 d . . .
F1 F 0.46500(14) -0.20232(5) 0.13522(11) 0.0451(4) Uani 1 1 d . . .
F2 F 0.36053(16) -0.26311(6) 0.16226(12) 0.0519(4) Uani 1 1 d . . .
F3 F 0.29259(15) -0.18996(8) 0.15894(16) 0.0746(7) Uani 1 1 d . . .
F4 F 0.43816(16) -0.20910(10) 0.25540(13) 0.0737(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C48 Rh1 C49 37.07(5) . . ?
C48 Rh1 C51 77.71(6) . . ?
C49 Rh1 C51 65.54(6) . . ?
C48 Rh1 C52 65.50(6) . . ?
C49 Rh1 C52 77.77(5) . . ?
C51 Rh1 C52 37.04(6) . . ?
C48 Rh1 P2 148.60(4) . . ?
C49 Rh1 P2 165.23(4) . . ?
C51 Rh1 P2 100.50(4) . . ?
C52 Rh1 P2 93.95(4) . . ?
C48 Rh1 P1 99.93(4) . . ?
C49 Rh1 P1 94.54(4) . . ?
C51 Rh1 P1 150.36(4) . . ?
C52 Rh1 P1 164.02(4) . . ?
P2 Rh1 P1 96.312(13) . . ?
C8 P1 C30 111.19(6) . . ?
C8 P1 C24 98.65(6) . . ?
C30 P1 C24 107.75(7) . . ?
C8 P1 Rh1 110.43(5) . . ?
C30 P1 Rh1 113.86(4) . . ?
C24 P1 Rh1 113.94(4) . . ?
O1 C1 O2 106.91(10) . . ?
O1 C1 C2 112.71(10) . . ?
O2 C1 C2 104.85(12) . . ?
O1 C1 C13 104.83(12) . . ?
O2 C1 C13 112.36(10) . . ?
C2 C1 C13 115.05(11) . . ?
C9 O1 C1 115.23(11) . . ?
C19 P2 C42 111.30(6) . . ?
C19 P2 C36 98.54(6) . . ?
C42 P2 C36 107.92(7) . . ?
C19 P2 Rh1 110.06(5) . . ?
C42 P2 Rh1 112.81(4) . . ?
C36 P2 Rh1 115.36(4) . . ?
C1 C2 C3 113.66(12) . . ?
C20 O2 C1 114.85(11) . . ?
C4 C3 C11 112.89(13) . . ?
C4 C3 C10 110.51(13) . . ?
C11 C3 C10 108.87(13) . . ?
C4 C3 C2 105.26(11) . . ?
C11 C3 C2 108.02(13) . . ?
C10 C3 C2 111.24(13) . . ?
C5 C4 C9 118.45(12) . . ?
C5 C4 C3 124.92(12) . . ?
C9 C4 C3 116.59(12) . . ?
C4 C5 C6 121.61(13) . . ?
C7 C6 C5 118.24(13) . . ?
C7 C6 C12 121.53(14) . . ?
C5 C6 C12 120.20(14) . . ?
C6 C7 C8 122.41(13) . . ?
C9 C8 C7 116.93(12) . . ?
C9 C8 P1 128.14(10) . . ?
C7 C8 P1 114.92(9) . . ?
O1 C9 C8 120.12(11) . . ?
O1 C9 C4 117.59(11) . . ?
C8 C9 C4 122.25(12) . . ?
C1 C13 C14 113.53(12) . . ?
C15 C14 C21 113.09(13) . . ?
C15 C14 C22 110.21(14) . . ?
C21 C14 C22 108.88(14) . . ?
C15 C14 C13 105.26(11) . . ?
C21 C14 C13 107.95(14) . . ?
C22 C14 C13 111.43(13) . . ?
C16 C15 C20 118.81(12) . . ?
C16 C15 C14 125.21(13) . . ?
C20 C15 C14 115.96(12) . . ?
C15 C16 C17 121.02(13) . . ?
C18 C17 C16 118.63(13) . . ?
C18 C17 C23 120.73(14) . . ?
C16 C17 C23 120.62(14) . . ?
C17 C18 C19 122.28(13) . . ?
C20 C19 C18 117.03(12) . . ?
C20 C19 P2 128.44(10) . . ?
C18 C19 P2 114.52(9) . . ?
O2 C20 C19 120.08(12) . . ?
O2 C20 C15 117.74(11) . . ?
C19 C20 C15 122.15(12) . . ?
C25 C24 C29 109.10(12) . . ?
C25 C24 P1 114.34(9) . . ?
C29 C24 P1 117.16(9) . . ?
C26 C25 C24 110.10(11) . . ?
C27 C26 C25 110.85(11) . . ?
C26 C27 C28 111.08(13) . . ?
C27 C28 C29 111.57(12) . . ?
C28 C29 C24 109.67(11) . . ?
C31 C30 C35 110.51(12) . . ?
C31 C30 P1 116.06(9) . . ?
C35 C30 P1 110.13(9) . . ?
C32 C31 C30 111.04(12) . . ?
C33 C32 C31 111.16(13) . . ?
C34 C33 C32 110.83(15) . . ?
C33 C34 C35 111.53(12) . . ?
C34 C35 C30 110.57(12) . . ?
C41 C36 C37 109.79(12) . . ?
C41 C36 P2 113.94(9) . . ?
C37 C36 P2 116.16(9) . . ?
C38 C37 C36 109.92(11) . . ?
C39 C38 C37 110.90(13) . . ?
C38 C39 C40 111.00(14) . . ?
C39 C40 C41 110.84(12) . . ?
C40 C41 C36 110.66(12) . . ?
C43 C42 C47 110.94(13) . . ?
C43 C42 P2 117.06(10) . . ?
C47 C42 P2 109.68(9) . . ?
C44 C43 C42 110.81(13) . . ?
C45 C44 C43 111.33(13) . . ?
C44 C45 C46 110.81(15) . . ?
C47 C46 C45 111.85(14) . . ?
C46 C47 C42 110.76(12) . . ?
C49 C48 C53 106.69(13) . . ?
C49 C48 Rh1 71.70(8) . . ?
C53 C48 Rh1 96.73(9) . . ?
C48 C49 C50 106.29(12) . . ?
C48 C49 Rh1 71.23(8) . . ?
C50 C49 Rh1 96.73(9) . . ?
C49 C50 C51 101.06(11) . . ?
C49 C50 C54 100.54(13) . . ?
C51 C50 C54 100.26(12) . . ?
C52 C51 C50 106.32(13) . . ?
C52 C51 Rh1 71.62(8) . . ?
C50 C51 Rh1 96.51(10) . . ?
C51 C52 C53 106.51(12) . . ?
C51 C52 Rh1 71.34(8) . . ?
C53 C52 Rh1 96.38(9) . . ?
C52 C53 C48 101.20(11) . . ?
C52 C53 C54 100.49(13) . . ?
C48 C53 C54 100.43(11) . . ?
C53 C54 C50 93.91(10) . . ?
Cl3B C1LB Cl1B 110.34(15) . . ?
Cl3B C1LB Cl2B 111.09(15) . . ?
Cl1B C1LB Cl2B 110.11(12) . . ?
Cl1' C1LA Cl2A 119.8(2) . . ?
Cl1' C1LA Cl3A 89.2(3) . . ?
Cl2A C1LA Cl3A 112.00(19) . . ?
Cl1' C1LA Cl3' 115.6(4) . . ?
Cl2A C1LA Cl3' 83.2(3) . . ?
Cl3A C1LA Cl3' 31.6(3) . . ?
Cl1' C1LA Cl1A 18.6(2) . . ?
Cl2A C1LA Cl1A 107.79(13) . . ?
Cl3A C1LA Cl1A 107.50(16) . . ?
Cl3' C1LA Cl1A 131.4(4) . . ?
Cl1' C1LA Cl2' 112.6(6) . . ?
Cl2A C1LA Cl2' 37.7(5) . . ?
Cl3A C1LA Cl2' 148.4(6) . . ?
Cl3' C1LA Cl2' 117.2(6) . . ?
Cl1A C1LA Cl2' 94.4(5) . . ?
F3 B1 F1 118.0(3) . . ?
F3 B1 F2 108.7(2) . . ?
F1 B1 F2 112.1(2) . . ?
F3 B1 F4 105.2(2) . . ?
F1 B1 F4 105.3(2) . . ?
F2 B1 F4 106.6(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C48 2.1865(14) . ?
Rh1 C49 2.1925(13) . ?
Rh1 C51 2.1925(15) . ?
Rh1 C52 2.1961(13) . ?
Rh1 P2 2.3776(4) . ?
Rh1 P1 2.3832(4) . ?
P1 C8 1.8386(13) . ?
P1 C30 1.8555(14) . ?
P1 C24 1.8763(14) . ?
C1 O1 1.4362(17) . ?
C1 O2 1.4407(17) . ?
C1 C2 1.534(2) . ?
C1 C13 1.535(2) . ?
O1 C9 1.3830(16) . ?
P2 C19 1.8327(14) . ?
P2 C42 1.8546(14) . ?
P2 C36 1.8796(14) . ?
C2 C3 1.5439(19) . ?
O2 C20 1.3839(16) . ?
C3 C4 1.5175(19) . ?
C3 C11 1.533(2) . ?
C3 C10 1.540(3) . ?
C4 C5 1.387(2) . ?
C4 C9 1.4039(18) . ?
C5 C6 1.401(2) . ?
C6 C7 1.389(2) . ?
C6 C12 1.512(2) . ?
C7 C8 1.4127(19) . ?
C8 C9 1.3953(18) . ?
C13 C14 1.543(2) . ?
C14 C15 1.5170(19) . ?
C14 C21 1.533(2) . ?
C14 C22 1.541(3) . ?
C15 C16 1.391(2) . ?
C15 C20 1.4037(19) . ?
C16 C17 1.401(2) . ?
C17 C18 1.389(2) . ?
C17 C23 1.511(2) . ?
C18 C19 1.4134(19) . ?
C19 C20 1.3920(17) . ?
C24 C25 1.540(2) . ?
C24 C29 1.5453(18) . ?
C25 C26 1.5310(19) . ?
C26 C27 1.527(2) . ?
C27 C28 1.530(2) . ?
C28 C29 1.533(2) . ?
C30 C31 1.539(2) . ?
C30 C35 1.5449(19) . ?
C31 C32 1.533(2) . ?
C32 C33 1.530(2) . ?
C33 C34 1.524(3) . ?
C34 C35 1.533(2) . ?
C36 C41 1.540(2) . ?
C36 C37 1.5442(19) . ?
C37 C38 1.533(2) . ?
C38 C39 1.528(2) . ?
C39 C40 1.529(2) . ?
C40 C41 1.535(2) . ?
C42 C43 1.536(2) . ?
C42 C47 1.5434(19) . ?
C43 C44 1.532(2) . ?
C44 C45 1.528(3) . ?
C45 C46 1.529(3) . ?
C46 C47 1.529(2) . ?
C48 C49 1.392(2) . ?
C48 C53 1.535(2) . ?
C49 C50 1.534(2) . ?
C50 C51 1.541(2) . ?
C50 C54 1.551(2) . ?
C51 C52 1.394(2) . ?
C52 C53 1.533(2) . ?
C53 C54 1.545(2) . ?
Cl1B C1LB 1.752(2) . ?
C1LB Cl3B 1.727(3) . ?
C1LB Cl2B 1.754(2) . ?
C1LA Cl1' 1.554(6) . ?
C1LA Cl2A 1.729(3) . ?
C1LA Cl3A 1.757(3) . ?
C1LA Cl3' 1.779(10) . ?
C1LA Cl1A 1.800(3) . ?
C1LA Cl2' 1.811(15) . ?
B1 F3 1.341(3) . ?
B1 F1 1.349(3) . ?
B1 F2 1.371(3) . ?
B1 F4 1.435(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C48 Rh1 P1 C8 -152.63(6) . . . . ?
C49 Rh1 P1 C8 -115.63(6) . . . . ?
C51 Rh1 P1 C8 -70.06(10) . . . . ?
C52 Rh1 P1 C8 -175.99(14) . . . . ?
P2 Rh1 P1 C8 54.34(4) . . . . ?
C48 Rh1 P1 C30 81.45(6) . . . . ?
C49 Rh1 P1 C30 118.45(6) . . . . ?
C51 Rh1 P1 C30 164.02(10) . . . . ?
C52 Rh1 P1 C30 58.09(15) . . . . ?
P2 Rh1 P1 C30 -71.57(5) . . . . ?
C48 Rh1 P1 C24 -42.68(6) . . . . ?
C49 Rh1 P1 C24 -5.69(6) . . . . ?
C51 Rh1 P1 C24 39.89(10) . . . . ?
C52 Rh1 P1 C24 -66.05(15) . . . . ?
P2 Rh1 P1 C24 164.29(5) . . . . ?
O2 C1 O1 C9 -75.18(13) . . . . ?
C2 C1 O1 C9 39.51(15) . . . . ?
C13 C1 O1 C9 165.36(10) . . . . ?
C48 Rh1 P2 C19 -67.88(9) . . . . ?
C49 Rh1 P2 C19 -169.84(15) . . . . ?
C51 Rh1 P2 C19 -151.45(6) . . . . ?
C52 Rh1 P2 C19 -114.67(6) . . . . ?
P1 Rh1 P2 C19 53.07(4) . . . . ?
C48 Rh1 P2 C42 167.15(9) . . . . ?
C49 Rh1 P2 C42 65.20(15) . . . . ?
C51 Rh1 P2 C42 83.58(7) . . . . ?
C52 Rh1 P2 C42 120.36(7) . . . . ?
P1 Rh1 P2 C42 -71.90(5) . . . . ?
C48 Rh1 P2 C36 42.50(10) . . . . ?
C49 Rh1 P2 C36 -59.46(16) . . . . ?
C51 Rh1 P2 C36 -41.07(7) . . . . ?
C52 Rh1 P2 C36 -4.29(7) . . . . ?
P1 Rh1 P2 C36 163.45(5) . . . . ?
O1 C1 C2 C3 13.16(17) . . . . ?
O2 C1 C2 C3 129.08(12) . . . . ?
C13 C1 C2 C3 -106.97(14) . . . . ?
O1 C1 O2 C20 -73.58(13) . . . . ?
C2 C1 O2 C20 166.55(10) . . . . ?
C13 C1 O2 C20 40.90(15) . . . . ?
C1 C2 C3 C4 -52.64(17) . . . . ?
C1 C2 C3 C11 -173.49(13) . . . . ?
C1 C2 C3 C10 67.08(15) . . . . ?
C11 C3 C4 C5 -14.5(2) . . . . ?
C10 C3 C4 C5 107.74(18) . . . . ?
C2 C3 C4 C5 -132.06(17) . . . . ?
C11 C3 C4 C9 163.16(15) . . . . ?
C10 C3 C4 C9 -74.64(17) . . . . ?
C2 C3 C4 C9 45.56(19) . . . . ?
C9 C4 C5 C6 -1.6(3) . . . . ?
C3 C4 C5 C6 175.98(16) . . . . ?
C4 C5 C6 C7 1.4(3) . . . . ?
C4 C5 C6 C12 -176.68(16) . . . . ?
C5 C6 C7 C8 1.2(2) . . . . ?
C12 C6 C7 C8 179.29(16) . . . . ?
C6 C7 C8 C9 -3.5(2) . . . . ?
C6 C7 C8 P1 175.92(13) . . . . ?
C30 P1 C8 C9 13.19(16) . . . . ?
C24 P1 C8 C9 126.13(14) . . . . ?
Rh1 P1 C8 C9 -114.22(13) . . . . ?
C30 P1 C8 C7 -166.17(11) . . . . ?
C24 P1 C8 C7 -53.23(12) . . . . ?
Rh1 P1 C8 C7 66.43(12) . . . . ?
C1 O1 C9 C8 131.78(13) . . . . ?
C1 O1 C9 C4 -50.33(17) . . . . ?
C7 C8 C9 O1 -178.92(13) . . . . ?
P1 C8 C9 O1 1.7(2) . . . . ?
C7 C8 C9 C4 3.3(2) . . . . ?
P1 C8 C9 C4 -176.04(12) . . . . ?
C5 C4 C9 O1 -178.69(14) . . . . ?
C3 C4 C9 O1 3.5(2) . . . . ?
C5 C4 C9 C8 -0.9(2) . . . . ?
C3 C4 C9 C8 -178.63(14) . . . . ?
O1 C1 C13 C14 127.69(12) . . . . ?
O2 C1 C13 C14 11.94(17) . . . . ?
C2 C1 C13 C14 -107.94(14) . . . . ?
C1 C13 C14 C15 -53.01(17) . . . . ?
C1 C13 C14 C21 -174.05(13) . . . . ?
C1 C13 C14 C22 66.44(16) . . . . ?
C21 C14 C15 C16 -13.2(2) . . . . ?
C22 C14 C15 C16 108.95(18) . . . . ?
C13 C14 C15 C16 -130.79(17) . . . . ?
C21 C14 C15 C20 164.76(15) . . . . ?
C22 C14 C15 C20 -73.12(17) . . . . ?
C13 C14 C15 C20 47.14(19) . . . . ?
C20 C15 C16 C17 -0.8(2) . . . . ?
C14 C15 C16 C17 177.08(16) . . . . ?
C15 C16 C17 C18 1.4(3) . . . . ?
C15 C16 C17 C23 -176.85(16) . . . . ?
C16 C17 C18 C19 0.3(2) . . . . ?
C23 C17 C18 C19 178.58(15) . . . . ?
C17 C18 C19 C20 -2.6(2) . . . . ?
C17 C18 C19 P2 176.51(13) . . . . ?
C42 P2 C19 C20 10.76(16) . . . . ?
C36 P2 C19 C20 123.87(14) . . . . ?
Rh1 P2 C19 C20 -115.06(13) . . . . ?
C42 P2 C19 C18 -168.18(11) . . . . ?
C36 P2 C19 C18 -55.07(12) . . . . ?
Rh1 P2 C19 C18 65.99(11) . . . . ?
C1 O2 C20 C19 131.34(13) . . . . ?
C1 O2 C20 C15 -50.57(17) . . . . ?
C18 C19 C20 O2 -178.80(13) . . . . ?
P2 C19 C20 O2 2.3(2) . . . . ?
C18 C19 C20 C15 3.2(2) . . . . ?
P2 C19 C20 C15 -175.73(12) . . . . ?
C16 C15 C20 O2 -179.64(14) . . . . ?
C14 C15 C20 O2 2.3(2) . . . . ?
C16 C15 C20 C19 -1.6(2) . . . . ?
C14 C15 C20 C19 -179.66(14) . . . . ?
C8 P1 C24 C25 -170.07(10) . . . . ?
C30 P1 C24 C25 -54.44(11) . . . . ?
Rh1 P1 C24 C25 72.93(11) . . . . ?
C8 P1 C24 C29 -40.59(12) . . . . ?
C30 P1 C24 C29 75.04(12) . . . . ?
Rh1 P1 C24 C29 -157.59(10) . . . . ?
C29 C24 C25 C26 60.19(15) . . . . ?
P1 C24 C25 C26 -166.43(10) . . . . ?
C24 C25 C26 C27 -58.33(17) . . . . ?
C25 C26 C27 C28 55.34(18) . . . . ?
C26 C27 C28 C29 -55.16(18) . . . . ?
C27 C28 C29 C24 57.22(18) . . . . ?
C25 C24 C29 C28 -59.33(16) . . . . ?
P1 C24 C29 C28 168.76(11) . . . . ?
C8 P1 C30 C31 64.74(12) . . . . ?
C24 P1 C30 C31 -42.33(12) . . . . ?
Rh1 P1 C30 C31 -169.74(9) . . . . ?
C8 P1 C30 C35 -168.77(10) . . . . ?
C24 P1 C30 C35 84.16(11) . . . . ?
Rh1 P1 C30 C35 -43.25(11) . . . . ?
C35 C30 C31 C32 55.97(16) . . . . ?
P1 C30 C31 C32 -177.74(11) . . . . ?
C30 C31 C32 C33 -56.23(19) . . . . ?
C31 C32 C33 C34 56.2(2) . . . . ?
C32 C33 C34 C35 -56.54(19) . . . . ?
C33 C34 C35 C30 56.49(18) . . . . ?
C31 C30 C35 C34 -55.86(16) . . . . ?
P1 C30 C35 C34 174.60(11) . . . . ?
C19 P2 C36 C41 -169.40(10) . . . . ?
C42 P2 C36 C41 -53.64(11) . . . . ?
Rh1 P2 C36 C41 73.52(11) . . . . ?
C19 P2 C36 C37 -40.29(13) . . . . ?
C42 P2 C36 C37 75.47(13) . . . . ?
Rh1 P2 C36 C37 -157.37(10) . . . . ?
C41 C36 C37 C38 -58.35(17) . . . . ?
P2 C36 C37 C38 170.56(12) . . . . ?
C36 C37 C38 C39 58.04(18) . . . . ?
C37 C38 C39 C40 -56.91(18) . . . . ?
C38 C39 C40 C41 55.99(19) . . . . ?
C39 C40 C41 C36 -56.77(18) . . . . ?
C37 C36 C41 C40 57.91(15) . . . . ?
P2 C36 C41 C40 -169.83(10) . . . . ?
C19 P2 C42 C43 65.02(12) . . . . ?
C36 P2 C42 C43 -42.06(12) . . . . ?
Rh1 P2 C42 C43 -170.69(9) . . . . ?
C19 P2 C42 C47 -167.47(10) . . . . ?
C36 P2 C42 C47 85.45(11) . . . . ?
Rh1 P2 C42 C47 -43.18(11) . . . . ?
C47 C42 C43 C44 55.94(17) . . . . ?
P2 C42 C43 C44 -177.16(11) . . . . ?
C42 C43 C44 C45 -56.5(2) . . . . ?
C43 C44 C45 C46 56.1(2) . . . . ?
C44 C45 C46 C47 -55.7(2) . . . . ?
C45 C46 C47 C42 55.4(2) . . . . ?
C43 C42 C47 C46 -55.30(17) . . . . ?
P2 C42 C47 C46 173.84(12) . . . . ?
C51 Rh1 C48 C49 -65.51(9) . . . . ?
C52 Rh1 C48 C49 -102.53(10) . . . . ?
P2 Rh1 C48 C49 -155.57(7) . . . . ?
P1 Rh1 C48 C49 84.36(8) . . . . ?
C49 Rh1 C48 C53 105.40(13) . . . . ?
C51 Rh1 C48 C53 39.88(9) . . . . ?
C52 Rh1 C48 C53 2.87(8) . . . . ?
P2 Rh1 C48 C53 -50.17(13) . . . . ?
P1 Rh1 C48 C53 -170.24(8) . . . . ?
C53 C48 C49 C50 0.00(15) . . . . ?
Rh1 C48 C49 C50 91.70(10) . . . . ?
C53 C48 C49 Rh1 -91.70(10) . . . . ?
C51 Rh1 C49 C48 102.36(10) . . . . ?
C52 Rh1 C49 C48 65.36(9) . . . . ?
P2 Rh1 C49 C48 122.28(14) . . . . ?
P1 Rh1 C49 C48 -100.47(8) . . . . ?
C48 Rh1 C49 C50 -104.97(12) . . . . ?
C51 Rh1 C49 C50 -2.61(9) . . . . ?
C52 Rh1 C49 C50 -39.61(9) . . . . ?
P2 Rh1 C49 C50 17.3(2) . . . . ?
P1 Rh1 C49 C50 154.56(8) . . . . ?
C48 C49 C50 C51 -68.92(14) . . . . ?
Rh1 C49 C50 C51 3.44(11) . . . . ?
C48 C49 C50 C54 33.85(14) . . . . ?
Rh1 C49 C50 C54 106.21(9) . . . . ?
C49 C50 C51 C52 69.26(14) . . . . ?
C54 C50 C51 C52 -33.73(15) . . . . ?
C49 C50 C51 Rh1 -3.44(11) . . . . ?
C54 C50 C51 Rh1 -106.44(10) . . . . ?
C48 Rh1 C51 C52 -65.43(9) . . . . ?
C49 Rh1 C51 C52 -102.48(10) . . . . ?
P2 Rh1 C51 C52 82.58(9) . . . . ?
P1 Rh1 C51 C52 -153.93(8) . . . . ?
C48 Rh1 C51 C50 39.65(9) . . . . ?
C49 Rh1 C51 C50 2.59(9) . . . . ?
C52 Rh1 C51 C50 105.08(13) . . . . ?
P2 Rh1 C51 C50 -172.34(8) . . . . ?
P1 Rh1 C51 C50 -48.85(14) . . . . ?
C50 C51 C52 C53 -0.28(15) . . . . ?
Rh1 C51 C52 C53 91.28(10) . . . . ?
C50 C51 C52 Rh1 -91.56(10) . . . . ?
C48 Rh1 C52 C51 102.45(10) . . . . ?
C49 Rh1 C52 C51 65.42(9) . . . . ?
P2 Rh1 C52 C51 -102.22(8) . . . . ?
P1 Rh1 C52 C51 127.87(13) . . . . ?
C48 Rh1 C52 C53 -2.87(8) . . . . ?
C49 Rh1 C52 C53 -39.89(9) . . . . ?
C51 Rh1 C52 C53 -105.31(12) . . . . ?
P2 Rh1 C52 C53 152.47(8) . . . . ?
P1 Rh1 C52 C53 22.6(2) . . . . ?
C51 C52 C53 C48 -68.60(14) . . . . ?
Rh1 C52 C53 C48 3.79(11) . . . . ?
C51 C52 C53 C54 34.37(14) . . . . ?
Rh1 C52 C53 C54 106.76(9) . . . . ?
C49 C48 C53 C52 69.05(14) . . . . ?
Rh1 C48 C53 C52 -3.81(11) . . . . ?
C49 C48 C53 C54 -33.97(14) . . . . ?
Rh1 C48 C53 C54 -106.83(10) . . . . ?
C52 C53 C54 C50 -52.05(12) . . . . ?
C48 C53 C54 C50 51.54(13) . . . . ?
C49 C50 C54 C53 -51.67(12) . . . . ?
C51 C50 C54 C53 51.74(13) . . . . ?
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 168347323
