Structural, spectroscopic, and electrochemical behavior of trans-phenolato cobalt(III) complexes of asymmetric NN'O ligands as archetypes for metallomesogens.
Authors of publication
Shakya, Rajendra; Imbert, Camille; Hratchian, Hrant P.; Lanznaster, Mauricio; Heeg, Mary Jane; McGarvey, Bruce R.; Allard, Marco; Schlegel, H. Bernhard; Verani, Claudio N.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2006
Journal issue
21
Pages of publication
2517 - 2525
a
11.1872 ± 0.0006 Å
b
22.7813 ± 0.0013 Å
c
22.194 ± 0.0013 Å
α
90°
β
98.922 ± 0.002°
γ
90°
Cell volume
5587.9 ± 0.5 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0553
Residual factor for significantly intense reflections
0.0334
Weighted residual factors for significantly intense reflections
0.079
Weighted residual factors for all reflections included in the refinement
0.0853
Goodness-of-fit parameter for all reflections included in the refinement
