Information card for entry 7007597

Structure parameters

• Formula: C27 H23 Au Cr N O5 P
• Calculated formula: C27 H23 Au Cr N O5 P
• SMILES: [Cr](C#[O])(C#[O])(C#[O])(C#[O])(C#[O])CC(=[Au][P](c1ccccc1)(c1ccccc1)c1ccccc1)N(C)C
• Title of publication: Aurolysis of alpha-C-deprotonated group 6 aminocarbene and thiocarbene complexes with Ph3PAu+.
• Authors of publication: Raubenheimer, Helgard G.; Esterhuysen, Matthias W.; Frenking, Gernot; Timoshkin, Alexey Y.; Esterhuysen, Catharine; Horvath, Ulrike E. I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 38
• Pages of publication: 4580 - 4589
• a: 6.6251 ± 0.0002 Å
• b: 23.8365 ± 0.0008 Å
• c: 17.0238 ± 0.0005 Å
• α: 90°
• β: 97.573 ± 0.001°
• γ: 90°
• Cell volume: 2664.94 ± 0.14 ų
• Cell temperature: 178 ± 2 K
• Ambient diffraction temperature: 178 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0442
• Residual factor for significantly intense reflections: 0.0333
• Weighted residual factors for significantly intense reflections: 0.0832
• Weighted residual factors for all reflections included in the refinement: 0.089
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No