Information card for entry 7008157

Structure parameters

• Formula: C48 H18 Cl2 F36 P2 Pt
• Calculated formula: C48 H18 Cl2 F36 P2 Pt
• Title of publication: The electron-poor phosphines P{C6H3(CF3)2-3,5}3 and P(C6F5)3 do not mimic phosphites as ligands for hydroformylation. A comparison of the coordination chemistry of P{C6H3(CF3)2-3,5}3 and P(C6F5)3 and the unexpectedly low hydroformylation activity of their rhodium complexes.
• Authors of publication: Clarke, Matthew L.; Ellis, Dianne; Mason, Kate L.; Orpen, A. Guy; Pringle, Paul G.; Wingad, Richard L.; Zaher, Damien A.; Baker, R. Tom
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 7
• Pages of publication: 1294 - 1300
• a: 10.372 ± 0.002 Å
• b: 11.649 ± 0.002 Å
• c: 12.263 ± 0.003 Å
• α: 69.43 ± 0.02°
• β: 86.03 ± 0.02°
• γ: 85.137 ± 0.015°
• Cell volume: 1381 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.019
• Residual factor for significantly intense reflections: 0.019
• Weighted residual factors for all reflections: 0.0488
• Weighted residual factors for significantly intense reflections: 0.0488
• Goodness-of-fit parameter for all reflections: 1.027
• Goodness-of-fit parameter for significantly intense reflections: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No