Information card for entry 7008378

Structure parameters

• Chemical name: tetrakis((μ~3~-Sulfido)-(1,2-bis(diphenylarsino)ethane)-platinum)-copper(ii) bis(tetrafluoroborate) ethanol water solvate
• Formula: C106 H104 As8 B2 Cu F8 O2 Pt4 S4
• Calculated formula: C106 H102 As8 B2 Cu F8 O2 Pt4 S4
• Title of publication: Influence of the terminal ligands on the redox properties of the {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As) complexes and on their reactivity towards metal centres, protic acids and organic electrophiles.
• Authors of publication: Novio, Fernando; Mas-Ballesté, Rubén; Gallardo, Iluminada; González-Duarte, Pilar; Lledós, Agustí; Vila, Neus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 16
• Pages of publication: 2742 - 2753
• a: 26.419 ± 0.004 Å
• b: 14.858 ± 0.002 Å
• c: 29.009 ± 0.004 Å
• α: 90°
• β: 112.152 ± 0.002°
• γ: 90°
• Cell volume: 10546 ± 3 ų
• Cell temperature: 120 ± 0.1 K
• Ambient diffraction temperature: 120 ± 0.1 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1249
• Residual factor for significantly intense reflections: 0.0598
• Weighted residual factors for significantly intense reflections: 0.1395
• Weighted residual factors for all reflections included in the refinement: 0.1636
• Goodness-of-fit parameter for all reflections included in the refinement: 0.907
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No