Information card for entry 7008551

Structure parameters

• Formula: C50 H88 Cl4 Rh4 S4 Si2
• Calculated formula: C50 H88 Cl4 Rh4 S4 Si2
• Title of publication: Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes.
• Authors of publication: Camerano, José A; Casado, Miguel A.; Ciriano, Miguel A.; Tejel, Cristina; Oro, Luis A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 18
• Pages of publication: 3092 - 3100
• a: 19.6558 ± 0.0017 Å
• b: 12.1246 ± 0.0011 Å
• c: 24.755 ± 0.002 Å
• α: 90°
• β: 95.801 ± 0.002°
• γ: 90°
• Cell volume: 5869.4 ± 0.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.104
• Residual factor for significantly intense reflections: 0.0493
• Weighted residual factors for significantly intense reflections: 0.0729
• Weighted residual factors for all reflections included in the refinement: 0.0851
• Goodness-of-fit parameter for all reflections included in the refinement: 0.772
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No