Information card for entry 7010868

Structure parameters

• Formula: C41 H22 Cl3 O7 P Ru2 S4
• Calculated formula: C41 H22 Cl3 O7 P Ru2 S4
• SMILES: C(#[O])[Ru]12345(C#[O])[C]6(=[CH]1C=CO6)[CH]12=[C]2(c6ccc(c7ccc(C#C)s7)s6)[CH]6=[C]3(c3ccc(c7ccc(C#C)s7)s3)[Ru]5126(C#[O])(C#[O])[P]4(c1ccco1)c1ccco1.C(Cl)(Cl)Cl
• Title of publication: A new family of phosphido-bridged dinuclear ruthenium carbonyl complexes: synthesis of [Ru2(CO)6{µ-P(C(CH)3O)2}(µ-η1,η2-C(CH)3O)] and its reactivity towards terminal alkynes
• Authors of publication: Wong, Wai-Yeung; Ting, Fai-Lung; Lam, Wai-Lim
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 20
• Pages of publication: 2981
• a: 11.7185 ± 0.0008 Å
• b: 13.41 ± 0.0009 Å
• c: 15.2078 ± 0.0011 Å
• α: 109.347 ± 0.001°
• β: 102.311 ± 0.001°
• γ: 98.329 ± 0.001°
• Cell volume: 2142 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1026
• Residual factor for significantly intense reflections: 0.0615
• Weighted residual factors for significantly intense reflections: 0.1641
• Weighted residual factors for all reflections included in the refinement: 0.1885
• Goodness-of-fit parameter for all reflections included in the refinement: 0.943
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No