#------------------------------------------------------------------------------
#$Date: 2025-08-21 13:21:36 +0200 (Thu 21 de Aug de 2025) $
#$Revision: 301847 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/14/7011455.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7011455
loop_
_publ_author_name
'Koshevoy, Igor O.'
'Tunik, Sergey P.'
'Jääskeläinen, Sirpa'
'Haukka, Matti'
'Pakkanen, Tapani A.'
'Podkorytov, Ivan S.'
_publ_section_title
;
 Synthesis and structural characterization of mixed-metal Pt--Rh
 clusters. Assembly of tetra- and tetra-hexanuclear clusters from
 smaller metal fragments
;
_journal_issue                   13
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2768
_journal_paper_doi               10.1039/b200003b
_journal_year                    2002
_chemical_formula_sum            'C56.5 H46 O6.5 P4 Pt2 Rh2'
_chemical_formula_weight         1548.81
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.8680(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.7311(2)
_cell_length_b                   29.1268(3)
_cell_length_c                   13.8315(3)
_cell_measurement_temperature    120(2)
_cell_volume                     5432.59(15)
_computing_cell_refinement       'Denzo/Scalepack (Otwinowski & Minor, 1997)'
_computing_data_collection       'Collect (Nonius, 1999)'
_computing_data_reduction        'Denzo/Scalepack (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'XP in SHELXTL v.5.1 (Bruker Axs, 1998)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al., 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.884
_diffrn_measured_fraction_theta_max 0.884
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0422
_diffrn_reflns_av_sigmaI/netI    0.0404
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            31093
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.32
_exptl_absorpt_coefficient_mu    5.898
_exptl_absorpt_correction_T_max  0.3850
_exptl_absorpt_correction_T_min  0.2706
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Xprep in Shelxtl v. 5.1, Bruker AXS, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.894
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2972
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.213
_refine_diff_density_min         -1.581
_refine_diff_density_rms         0.240
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     644
_refine_ls_number_reflns         8513
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0373
_refine_ls_R_factor_gt           0.0288
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0226P)²+16.3486P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0643
_refine_ls_wR_factor_ref         0.0671
_reflns_number_gt                7563
_reflns_number_total             8513
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b200003b.txt
_cod_data_source_block           structure1b
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C56.50 H46 O6.50 P4 Pt2 Rh2'
_cod_database_code               7011455
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.834551(16) 0.411490(6) 0.495169(17) 0.02057(7) Uani 1 1 d . . .
Pt2 Pt 0.710489(15) 0.329201(6) 0.419519(15) 0.01533(6) Uani 1 1 d . . .
Rh1 Rh 0.84266(3) 0.365919(12) 0.32851(3) 0.01534(10) Uani 1 1 d . . .
Rh2 Rh 0.67809(3) 0.412527(13) 0.34450(4) 0.02003(11) Uani 1 1 d . . .
P1 P 0.90582(10) 0.42434(4) 0.24098(12) 0.0218(3) Uani 1 1 d . . .
P2 P 0.72080(11) 0.47941(5) 0.27134(13) 0.0272(4) Uani 1 1 d . . .
P3 P 0.89719(10) 0.29541(4) 0.28722(10) 0.0145(3) Uani 1 1 d . . .
P4 P 0.79781(10) 0.26261(4) 0.45859(10) 0.0142(3) Uani 1 1 d . . .
O1 O 0.9529(4) 0.43639(15) 0.6943(4) 0.0417(12) Uani 1 1 d . . .
O2 O 1.0200(3) 0.35304(12) 0.4954(3) 0.0251(9) Uani 1 1 d . . .
O3 O 0.6437(3) 0.45447(15) 0.5382(4) 0.0446(12) Uani 1 1 d . . .
O4 O 0.5247(3) 0.31665(15) 0.5028(4) 0.0463(12) Uani 1 1 d . . .
O5 O 0.6619(3) 0.34925(12) 0.1640(3) 0.0249(9) Uani 1 1 d . . .
O6 O 0.4547(3) 0.41283(15) 0.2747(4) 0.0486(13) Uani 1 1 d . . .
C1 C 0.9057(4) 0.42820(19) 0.6194(5) 0.0262(13) Uani 1 1 d . . .
C2 C 0.9451(4) 0.36768(16) 0.4537(4) 0.0176(12) Uani 1 1 d . . .
C3 C 0.6919(4) 0.43771(19) 0.4872(5) 0.0319(15) Uani 1 1 d . . .
C4 C 0.5955(4) 0.32137(18) 0.4700(4) 0.0247(13) Uani 1 1 d . . .
C5 C 0.7088(4) 0.36440(17) 0.2364(5) 0.0200(12) Uani 1 1 d . . .
C6 C 0.5392(5) 0.41338(18) 0.3028(5) 0.0301(15) Uani 1 1 d . . .
C7 C 0.8553(4) 0.48028(17) 0.2729(5) 0.0271(14) Uani 1 1 d . . .
H7A H 0.8901 0.4895 0.3394 0.033 Uiso 1 1 calc R . .
H7B H 0.8695 0.5038 0.2258 0.033 Uiso 1 1 calc R . .
C8 C 1.0381(4) 0.43819(16) 0.2684(5) 0.0240(13) Uani 1 1 d . . .
C9 C 1.0815(4) 0.45117(18) 0.3631(5) 0.0307(15) Uani 1 1 d . . .
H9 H 1.0414 0.4531 0.4119 0.037 Uiso 1 1 calc R . .
C10 C 1.1818(5) 0.46145(19) 0.3891(6) 0.0361(16) Uani 1 1 d . . .
H10 H 1.2096 0.4711 0.4541 0.043 Uiso 1 1 calc R . .
C11 C 1.2407(5) 0.45737(19) 0.3182(6) 0.0362(17) Uani 1 1 d . . .
H11 H 1.3096 0.4639 0.3346 0.043 Uiso 1 1 calc R . .
C12 C 1.1992(4) 0.4439(2) 0.2245(6) 0.0355(16) Uani 1 1 d . . .
H12 H 1.2399 0.4409 0.1765 0.043 Uiso 1 1 calc R . .
C13 C 1.0992(4) 0.43453(17) 0.1991(5) 0.0279(14) Uani 1 1 d . . .
H13 H 1.0717 0.4255 0.1336 0.034 Uiso 1 1 calc R . .
C14 C 0.7008(4) 0.53223(18) 0.3355(6) 0.0351(16) Uani 1 1 d . . .
C15 C 0.7702(5) 0.56775(19) 0.3528(5) 0.0368(17) Uani 1 1 d . . .
H15 H 0.8324 0.5644 0.3330 0.044 Uiso 1 1 calc R . .
C16 C 0.7490(5) 0.6082(2) 0.3989(6) 0.050(2) Uani 1 1 d . . .
H16 H 0.7963 0.6324 0.4090 0.060 Uiso 1 1 calc R . .
C17 C 0.6598(6) 0.6132(2) 0.4298(9) 0.088(4) Uani 1 1 d . . .
H17 H 0.6456 0.6407 0.4616 0.105 Uiso 1 1 calc R . .
C18 C 0.5903(6) 0.5775(3) 0.4137(11) 0.111(5) Uani 1 1 d . . .
H18 H 0.5290 0.5804 0.4355 0.134 Uiso 1 1 calc R . .
C19 C 0.6112(5) 0.5380(2) 0.3660(8) 0.073(3) Uani 1 1 d . . .
H19 H 0.5629 0.5142 0.3539 0.088 Uiso 1 1 calc R . .
C20 C 0.6709(4) 0.4929(2) 0.1428(6) 0.0383(17) Uani 1 1 d . . .
C21 C 0.6775(5) 0.5373(2) 0.1054(6) 0.053(2) Uani 1 1 d . . .
H21 H 0.7024 0.5614 0.1494 0.064 Uiso 1 1 calc R . .
C22 C 0.6495(6) 0.5469(3) 0.0084(8) 0.066(3) Uani 1 1 d . . .
H22 H 0.6541 0.5774 -0.0142 0.080 Uiso 1 1 calc R . .
C23 C 0.6147(5) 0.5131(3) -0.0569(7) 0.058(2) Uani 1 1 d . . .
H23 H 0.5965 0.5199 -0.1251 0.069 Uiso 1 1 calc R . .
C24 C 0.6061(5) 0.4687(3) -0.0231(6) 0.0472(19) Uani 1 1 d . . .
H24 H 0.5815 0.4449 -0.0682 0.057 Uiso 1 1 calc R . .
C25 C 0.6332(5) 0.4590(2) 0.0764(5) 0.0391(17) Uani 1 1 d . . .
H25 H 0.6259 0.4287 0.0993 0.047 Uiso 1 1 calc R . .
C26 C 0.8784(4) 0.42260(19) 0.1069(5) 0.0289(14) Uani 1 1 d . . .
C27 C 0.8887(5) 0.4606(2) 0.0473(5) 0.0386(17) Uani 1 1 d . . .
H27 H 0.9097 0.4892 0.0771 0.046 Uiso 1 1 calc R . .
C28 C 0.8686(5) 0.4570(3) -0.0538(6) 0.048(2) Uani 1 1 d . . .
H28 H 0.8764 0.4830 -0.0930 0.057 Uiso 1 1 calc R . .
C29 C 0.8376(5) 0.4160(3) -0.0983(6) 0.0471(19) Uani 1 1 d . . .
H29 H 0.8232 0.4138 -0.1680 0.057 Uiso 1 1 calc R . .
C30 C 0.8273(5) 0.3778(2) -0.0406(5) 0.0391(16) Uani 1 1 d . . .
H30 H 0.8067 0.3493 -0.0709 0.047 Uiso 1 1 calc R . .
C31 C 0.8467(4) 0.3813(2) 0.0596(5) 0.0296(14) Uani 1 1 d . . .
H31 H 0.8386 0.3551 0.0982 0.035 Uiso 1 1 calc R . .
C32 C 0.8988(4) 0.25452(16) 0.3898(4) 0.0159(11) Uani 1 1 d . . .
H32A H 0.8949 0.2229 0.3630 0.019 Uiso 1 1 calc R . .
H32B H 0.9629 0.2575 0.4361 0.019 Uiso 1 1 calc R . .
C33 C 0.7249(4) 0.20980(16) 0.4453(4) 0.0159(11) Uani 1 1 d . . .
C34 C 0.7274(4) 0.17736(17) 0.3719(4) 0.0235(13) Uani 1 1 d . . .
H34 H 0.7720 0.1807 0.3276 0.028 Uiso 1 1 calc R . .
C35 C 0.6630(4) 0.13987(18) 0.3646(5) 0.0300(14) Uani 1 1 d . . .
H35 H 0.6633 0.1179 0.3139 0.036 Uiso 1 1 calc R . .
C36 C 0.5991(4) 0.13401(18) 0.4292(5) 0.0297(14) Uani 1 1 d . . .
H36 H 0.5563 0.1081 0.4233 0.036 Uiso 1 1 calc R . .
C37 C 0.5977(4) 0.16577(18) 0.5020(4) 0.0262(13) Uani 1 1 d . . .
H37 H 0.5545 0.1616 0.5475 0.031 Uiso 1 1 calc R . .
C38 C 0.6587(4) 0.20384(18) 0.5096(4) 0.0207(12) Uani 1 1 d . . .
H38 H 0.6555 0.2262 0.5590 0.025 Uiso 1 1 calc R . .
C39 C 0.8652(4) 0.26056(16) 0.5855(4) 0.0154(11) Uani 1 1 d . . .
C40 C 0.9174(4) 0.22078(18) 0.6219(4) 0.0211(12) Uani 1 1 d . . .
H40 H 0.9126 0.1938 0.5826 0.025 Uiso 1 1 calc R . .
C41 C 0.9760(4) 0.2208(2) 0.7154(4) 0.0280(14) Uani 1 1 d . . .
H41 H 1.0110 0.1939 0.7401 0.034 Uiso 1 1 calc R . .
C42 C 0.9833(4) 0.2603(2) 0.7729(4) 0.0259(13) Uani 1 1 d . . .
H42 H 1.0236 0.2602 0.8368 0.031 Uiso 1 1 calc R . .
C43 C 0.9326(4) 0.29946(19) 0.7377(4) 0.0271(14) Uani 1 1 d . . .
H43 H 0.9381 0.3264 0.7772 0.033 Uiso 1 1 calc R . .
C44 C 0.8732(4) 0.29955(18) 0.6442(4) 0.0214(12) Uani 1 1 d . . .
H44 H 0.8378 0.3265 0.6204 0.026 Uiso 1 1 calc R . .
C45 C 1.0244(4) 0.28666(16) 0.2707(4) 0.0158(11) Uani 1 1 d . . .
C46 C 1.0598(4) 0.24260(18) 0.2551(4) 0.0203(12) Uani 1 1 d . . .
H46 H 1.0157 0.2172 0.2472 0.024 Uiso 1 1 calc R . .
C47 C 1.1589(4) 0.23609(19) 0.2512(4) 0.0240(13) Uani 1 1 d . . .
H47 H 1.1825 0.2061 0.2412 0.029 Uiso 1 1 calc R . .
C48 C 1.2239(4) 0.27318(19) 0.2618(4) 0.0236(13) Uani 1 1 d . . .
H48 H 1.2919 0.2685 0.2594 0.028 Uiso 1 1 calc R . .
C49 C 1.1895(4) 0.31686(19) 0.2759(4) 0.0244(13) Uani 1 1 d . . .
H49 H 1.2336 0.3423 0.2821 0.029 Uiso 1 1 calc R . .
C50 C 1.0901(4) 0.32347(17) 0.2810(4) 0.0174(11) Uani 1 1 d . . .
H50 H 1.0669 0.3534 0.2915 0.021 Uiso 1 1 calc R . .
C51 C 0.8240(4) 0.26639(16) 0.1815(4) 0.0156(11) Uani 1 1 d . . .
C52 C 0.8593(4) 0.25984(17) 0.0944(4) 0.0214(12) Uani 1 1 d . . .
H52 H 0.9250 0.2689 0.0908 0.026 Uiso 1 1 calc R . .
C53 C 0.7992(4) 0.24013(18) 0.0128(4) 0.0245(13) Uani 1 1 d . . .
H53 H 0.8233 0.2364 -0.0468 0.029 Uiso 1 1 calc R . .
C54 C 0.7043(4) 0.22596(17) 0.0186(4) 0.0239(13) Uani 1 1 d . . .
H54 H 0.6638 0.2120 -0.0368 0.029 Uiso 1 1 calc R . .
C55 C 0.6682(4) 0.23191(17) 0.1040(4) 0.0216(12) Uani 1 1 d . . .
H55 H 0.6031 0.2219 0.1075 0.026 Uiso 1 1 calc R . .
C56 C 0.7265(3) 0.25237(15) 0.1843(4) 0.0186(12) Uani 1 1 d . . .
H56 H 0.7005 0.2571 0.2425 0.022 Uiso 1 1 calc R . .
O60 O 0.9703(3) 0.14783(15) 0.3603(4) 0.131(8) Uani 0.50 1 d PR . .
H601 H 1.0100 0.1200 0.3307 0.060 Uiso 0.50 1 d PR . .
C60 C 1.0491(3) 0.15053(15) 0.4401(4) 0.100(8) Uani 0.50 1 d PR . .
H60A H 1.0587 0.1825 0.4616 0.150 Uiso 0.50 1 calc PR . .
H60B H 1.1097 0.1392 0.4204 0.150 Uiso 0.50 1 calc PR . .
H60C H 1.0344 0.1317 0.4943 0.150 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C3 106.0(3) . . ?
C1 Pt1 C2 97.3(2) . . ?
C3 Pt1 C2 155.5(2) . . ?
C1 Pt1 Rh1 144.91(17) . . ?
C3 Pt1 Rh1 109.08(18) . . ?
C2 Pt1 Rh1 47.80(15) . . ?
C1 Pt1 Rh2 155.16(17) . . ?
C3 Pt1 Rh2 49.59(18) . . ?
C2 Pt1 Rh2 107.53(15) . . ?
Rh1 Pt1 Rh2 59.811(13) . . ?
C1 Pt1 Pt2 133.50(17) . . ?
C3 Pt1 Pt2 78.99(15) . . ?
C2 Pt1 Pt2 79.39(13) . . ?
Rh1 Pt1 Pt2 54.521(10) . . ?
Rh2 Pt1 Pt2 54.854(10) . . ?
C4 Pt2 P4 104.57(16) . . ?
C4 Pt2 Rh1 160.84(16) . . ?
P4 Pt2 Rh1 94.57(3) . . ?
C4 Pt2 Rh2 99.69(16) . . ?
P4 Pt2 Rh2 155.73(3) . . ?
Rh1 Pt2 Rh2 61.181(13) . . ?
C4 Pt2 Pt1 115.62(17) . . ?
P4 Pt2 Pt1 110.81(3) . . ?
Rh1 Pt2 Pt1 56.298(10) . . ?
Rh2 Pt2 Pt1 56.502(11) . . ?
C2 Rh1 C5 160.5(2) . . ?
C2 Rh1 P3 91.65(14) . . ?
C5 Rh1 P3 97.10(15) . . ?
C2 Rh1 P1 99.13(14) . . ?
C5 Rh1 P1 94.08(15) . . ?
P3 Rh1 P1 110.54(5) . . ?
C2 Rh1 Pt2 91.84(15) . . ?
C5 Rh1 Pt2 70.46(15) . . ?
P3 Rh1 Pt2 92.42(3) . . ?
P1 Rh1 Pt2 154.06(4) . . ?
C2 Rh1 Pt1 51.98(15) . . ?
C5 Rh1 Pt1 111.77(15) . . ?
P3 Rh1 Pt1 136.52(4) . . ?
P1 Rh1 Pt1 99.43(4) . . ?
Pt2 Rh1 Pt1 69.181(12) . . ?
C2 Rh1 Rh2 112.28(15) . . ?
C5 Rh1 Rh2 52.05(15) . . ?
P3 Rh1 Rh2 142.50(4) . . ?
P1 Rh1 Rh2 94.28(4) . . ?
Pt2 Rh1 Rh2 59.784(13) . . ?
Pt1 Rh1 Rh2 60.393(14) . . ?
C6 Rh2 C3 101.0(3) . . ?
C6 Rh2 C5 96.6(2) . . ?
C3 Rh2 C5 153.6(2) . . ?
C6 Rh2 P2 100.35(17) . . ?
C3 Rh2 P2 97.60(16) . . ?
C5 Rh2 P2 98.37(14) . . ?
C6 Rh2 Pt2 102.58(16) . . ?
C3 Rh2 Pt2 88.44(16) . . ?
C5 Rh2 Pt2 68.51(14) . . ?
P2 Rh2 Pt2 154.68(4) . . ?
C6 Rh2 Rh1 143.24(17) . . ?
C3 Rh2 Rh1 109.22(17) . . ?
C5 Rh2 Rh1 48.19(15) . . ?
P2 Rh2 Rh1 95.91(4) . . ?
Pt2 Rh2 Rh1 59.034(12) . . ?
C6 Rh2 Pt1 148.1(2) . . ?
C3 Rh2 Pt1 49.74(17) . . ?
C5 Rh2 Pt1 107.36(15) . . ?
P2 Rh2 Pt1 96.68(4) . . ?
Pt2 Rh2 Pt1 68.644(12) . . ?
Rh1 Rh2 Pt1 59.797(13) . . ?
C26 P1 C8 102.9(3) . . ?
C26 P1 C7 104.6(3) . . ?
C8 P1 C7 99.1(2) . . ?
C26 P1 Rh1 118.63(19) . . ?
C8 P1 Rh1 120.14(18) . . ?
C7 P1 Rh1 108.82(19) . . ?
C14 P2 C20 103.3(3) . . ?
C14 P2 C7 103.0(3) . . ?
C20 P2 C7 101.5(3) . . ?
C14 P2 Rh2 115.0(2) . . ?
C20 P2 Rh2 121.8(2) . . ?
C7 P2 Rh2 109.96(18) . . ?
C51 P3 C45 103.4(2) . . ?
C51 P3 C32 104.0(2) . . ?
C45 P3 C32 97.6(2) . . ?
C51 P3 Rh1 117.33(16) . . ?
C45 P3 Rh1 121.46(16) . . ?
C32 P3 Rh1 110.04(17) . . ?
C39 P4 C33 103.8(2) . . ?
C39 P4 C32 101.4(2) . . ?
C33 P4 C32 107.0(2) . . ?
C39 P4 Pt2 113.75(16) . . ?
C33 P4 Pt2 115.92(16) . . ?
C32 P4 Pt2 113.50(16) . . ?
O1 C1 Pt1 175.9(5) . . ?
O2 C2 Rh1 145.8(4) . . ?
O2 C2 Pt1 133.7(4) . . ?
Rh1 C2 Pt1 80.2(2) . . ?
O3 C3 Rh2 139.8(5) . . ?
O3 C3 Pt1 139.4(6) . . ?
Rh2 C3 Pt1 80.7(2) . . ?
O4 C4 Pt2 179.0(6) . . ?
O5 C5 Rh1 146.3(4) . . ?
O5 C5 Rh2 133.9(4) . . ?
Rh1 C5 Rh2 79.8(2) . . ?
O6 C6 Rh2 177.5(6) . . ?
P2 C7 P1 113.8(3) . . ?
P2 C7 H7A 108.8 . . ?
P1 C7 H7A 108.8 . . ?
P2 C7 H7B 108.8 . . ?
P1 C7 H7B 108.8 . . ?
H7A C7 H7B 107.7 . . ?
C9 C8 C13 117.6(5) . . ?
C9 C8 P1 119.3(4) . . ?
C13 C8 P1 123.0(5) . . ?
C8 C9 C10 122.2(6) . . ?
C8 C9 H9 118.9 . . ?
C10 C9 H9 118.9 . . ?
C9 C10 C11 118.6(7) . . ?
C9 C10 H10 120.7 . . ?
C11 C10 H10 120.7 . . ?
C12 C11 C10 119.9(6) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C11 C12 C13 120.9(6) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
C12 C13 C8 120.7(6) . . ?
C12 C13 H13 119.7 . . ?
C8 C13 H13 119.7 . . ?
C19 C14 C15 118.4(6) . . ?
C19 C14 P2 118.3(5) . . ?
C15 C14 P2 123.2(5) . . ?
C16 C15 C14 120.6(6) . . ?
C16 C15 H15 119.7 . . ?
C14 C15 H15 119.7 . . ?
C17 C16 C15 120.4(6) . . ?
C17 C16 H16 119.8 . . ?
C15 C16 H16 119.8 . . ?
C16 C17 C18 119.3(7) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C19 C18 C17 119.9(7) . . ?
C19 C18 H18 120.1 . . ?
C17 C18 H18 120.1 . . ?
C18 C19 C14 121.4(6) . . ?
C18 C19 H19 119.3 . . ?
C14 C19 H19 119.3 . . ?
C25 C20 C21 117.1(7) . . ?
C25 C20 P2 121.2(5) . . ?
C21 C20 P2 121.4(6) . . ?
C22 C21 C20 122.0(8) . . ?
C22 C21 H21 119.0 . . ?
C20 C21 H21 119.0 . . ?
C21 C22 C23 120.6(8) . . ?
C21 C22 H22 119.7 . . ?
C23 C22 H22 119.7 . . ?
C22 C23 C24 119.4(8) . . ?
C22 C23 H23 120.3 . . ?
C24 C23 H23 120.3 . . ?
C25 C24 C23 120.0(8) . . ?
C25 C24 H24 120.0 . . ?
C23 C24 H24 120.0 . . ?
C20 C25 C24 120.8(7) . . ?
C20 C25 H25 119.6 . . ?
C24 C25 H25 119.6 . . ?
C31 C26 C27 117.4(6) . . ?
C31 C26 P1 119.1(4) . . ?
C27 C26 P1 123.5(5) . . ?
C28 C27 C26 120.8(7) . . ?
C28 C27 H27 119.6 . . ?
C26 C27 H27 119.6 . . ?
C29 C28 C27 120.5(6) . . ?
C29 C28 H28 119.8 . . ?
C27 C28 H28 119.8 . . ?
C28 C29 C30 119.6(7) . . ?
C28 C29 H29 120.2 . . ?
C30 C29 H29 120.2 . . ?
C31 C30 C29 120.0(7) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C26 121.6(6) . . ?
C30 C31 H31 119.2 . . ?
C26 C31 H31 119.2 . . ?
P4 C32 P3 114.4(3) . . ?
P4 C32 H32A 108.7 . . ?
P3 C32 H32A 108.7 . . ?
P4 C32 H32B 108.7 . . ?
P3 C32 H32B 108.7 . . ?
H32A C32 H32B 107.6 . . ?
C34 C33 C38 119.2(5) . . ?
C34 C33 P4 123.9(4) . . ?
C38 C33 P4 116.8(4) . . ?
C33 C34 C35 118.8(5) . . ?
C33 C34 H34 120.6 . . ?
C35 C34 H34 120.6 . . ?
C36 C35 C34 121.5(6) . . ?
C36 C35 H35 119.3 . . ?
C34 C35 H35 119.3 . . ?
C37 C36 C35 119.6(5) . . ?
C37 C36 H36 120.2 . . ?
C35 C36 H36 120.2 . . ?
C36 C37 C38 120.3(6) . . ?
C36 C37 H37 119.9 . . ?
C38 C37 H37 119.9 . . ?
C37 C38 C33 120.6(5) . . ?
C37 C38 H38 119.7 . . ?
C33 C38 H38 119.7 . . ?
C44 C39 C40 119.0(5) . . ?
C44 C39 P4 120.4(4) . . ?
C40 C39 P4 120.3(4) . . ?
C41 C40 C39 120.0(5) . . ?
C41 C40 H40 120.0 . . ?
C39 C40 H40 120.0 . . ?
C40 C41 C42 120.0(5) . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C43 C42 C41 120.4(6) . . ?
C43 C42 H42 119.8 . . ?
C41 C42 H42 119.8 . . ?
C42 C43 C44 119.9(5) . . ?
C42 C43 H43 120.1 . . ?
C44 C43 H43 120.1 . . ?
C39 C44 C43 120.6(5) . . ?
C39 C44 H44 119.7 . . ?
C43 C44 H44 119.7 . . ?
C50 C45 C46 118.9(5) . . ?
C50 C45 P3 119.9(4) . . ?
C46 C45 P3 121.0(4) . . ?
C47 C46 C45 120.2(5) . . ?
C47 C46 H46 119.9 . . ?
C45 C46 H46 119.9 . . ?
C46 C47 C48 120.4(5) . . ?
C46 C47 H47 119.8 . . ?
C48 C47 H47 119.8 . . ?
C49 C48 C47 119.9(5) . . ?
C49 C48 H48 120.0 . . ?
C47 C48 H48 120.0 . . ?
C48 C49 C50 119.9(5) . . ?
C48 C49 H49 120.1 . . ?
C50 C49 H49 120.1 . . ?
C45 C50 C49 120.7(5) . . ?
C45 C50 H50 119.6 . . ?
C49 C50 H50 119.6 . . ?
C52 C51 C56 118.1(5) . . ?
C52 C51 P3 121.9(4) . . ?
C56 C51 P3 119.8(4) . . ?
C53 C52 C51 120.6(5) . . ?
C53 C52 H52 119.7 . . ?
C51 C52 H52 119.7 . . ?
C54 C53 C52 119.8(5) . . ?
C54 C53 H53 120.1 . . ?
C52 C53 H53 120.1 . . ?
C55 C54 C53 120.6(5) . . ?
C55 C54 H54 119.7 . . ?
C53 C54 H54 119.7 . . ?
C54 C55 C56 119.9(5) . . ?
C54 C55 H55 120.0 . . ?
C56 C55 H55 120.0 . . ?
C55 C56 C51 121.0(5) . . ?
C55 C56 H56 119.5 . . ?
C51 C56 H56 119.5 . . ?
C60 O60 H601 88.4 . . ?
O60 C60 H60A 109.5 . . ?
O60 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
O60 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.874(7) . ?
Pt1 C3 2.085(6) . ?
Pt1 C2 2.143(5) . ?
Pt1 Rh1 2.6804(5) . ?
Pt1 Rh2 2.6965(5) . ?
Pt1 Pt2 3.0115(3) . ?
Pt2 C4 1.857(6) . ?
Pt2 P4 2.2906(13) . ?
Pt2 Rh1 2.6237(4) . ?
Pt2 Rh2 2.6441(4) . ?
Rh1 C2 2.015(6) . ?
Rh1 C5 2.030(6) . ?
Rh1 P3 2.2948(13) . ?
Rh1 P1 2.3471(14) . ?
Rh1 Rh2 2.6808(6) . ?
Rh2 C6 1.886(7) . ?
Rh2 C3 2.081(7) . ?
Rh2 C5 2.148(6) . ?
Rh2 P2 2.3209(14) . ?
P1 C26 1.822(7) . ?
P1 C8 1.829(6) . ?
P1 C7 1.857(5) . ?
P2 C14 1.823(6) . ?
P2 C20 1.823(7) . ?
P2 C7 1.843(5) . ?
P3 C51 1.818(5) . ?
P3 C45 1.821(5) . ?
P3 C32 1.849(5) . ?
P4 C39 1.824(6) . ?
P4 C33 1.825(5) . ?
P4 C32 1.839(5) . ?
O1 C1 1.139(7) . ?
O2 C2 1.162(6) . ?
O3 C3 1.162(7) . ?
O4 C4 1.155(7) . ?
O5 C5 1.170(6) . ?
O6 C6 1.152(7) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.386(9) . ?
C8 C13 1.391(8) . ?
C9 C10 1.388(8) . ?
C9 H9 0.9500 . ?
C10 C11 1.389(9) . ?
C10 H10 0.9500 . ?
C11 C12 1.371(9) . ?
C11 H11 0.9500 . ?
C12 C13 1.379(8) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C19 1.384(9) . ?
C14 C15 1.397(8) . ?
C15 C16 1.396(9) . ?
C15 H15 0.9500 . ?
C16 C17 1.379(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.401(10) . ?
C17 H17 0.9500 . ?
C18 C19 1.384(11) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C25 1.382(10) . ?
C20 C21 1.403(9) . ?
C21 C22 1.352(12) . ?
C21 H21 0.9500 . ?
C22 C23 1.359(12) . ?
C22 H22 0.9500 . ?
C23 C24 1.389(10) . ?
C23 H23 0.9500 . ?
C24 C25 1.386(10) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C26 C31 1.397(9) . ?
C26 C27 1.403(8) . ?
C27 C28 1.377(10) . ?
C27 H27 0.9500 . ?
C28 C29 1.373(11) . ?
C28 H28 0.9500 . ?
C29 C30 1.392(10) . ?
C29 H29 0.9500 . ?
C30 C31 1.365(9) . ?
C30 H30 0.9500 . ?
C31 H31 0.9500 . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.392(8) . ?
C33 C38 1.398(7) . ?
C34 C35 1.396(8) . ?
C34 H34 0.9500 . ?
C35 C36 1.375(9) . ?
C35 H35 0.9500 . ?
C36 C37 1.371(8) . ?
C36 H36 0.9500 . ?
C37 C38 1.382(7) . ?
C37 H37 0.9500 . ?
C38 H38 0.9500 . ?
C39 C44 1.389(7) . ?
C39 C40 1.405(7) . ?
C40 C41 1.388(8) . ?
C40 H40 0.9500 . ?
C41 C42 1.390(8) . ?
C41 H41 0.9500 . ?
C42 C43 1.377(8) . ?
C42 H42 0.9500 . ?
C43 C44 1.393(8) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C50 1.391(7) . ?
C45 C46 1.404(7) . ?
C46 C47 1.384(7) . ?
C46 H46 0.9500 . ?
C47 C48 1.392(8) . ?
C47 H47 0.9500 . ?
C48 C49 1.384(8) . ?
C48 H48 0.9500 . ?
C49 C50 1.394(7) . ?
C49 H49 0.9500 . ?
C50 H50 0.9500 . ?
C51 C52 1.394(7) . ?
C51 C56 1.407(7) . ?
C52 C53 1.390(8) . ?
C52 H52 0.9500 . ?
C53 C54 1.383(8) . ?
C53 H53 0.9500 . ?
C54 C55 1.375(8) . ?
C54 H54 0.9500 . ?
C55 C56 1.377(7) . ?
C55 H55 0.9500 . ?
C56 H56 0.9500 . ?
O60 C60 1.3946 . ?
O60 H601 1.0966 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Pt1 Pt2 C4 64.9(3) . . . . ?
C3 Pt1 Pt2 C4 -36.8(3) . . . . ?
C2 Pt1 Pt2 C4 154.9(2) . . . . ?
Rh1 Pt1 Pt2 C4 -160.0(2) . . . . ?
Rh2 Pt1 Pt2 C4 -84.6(2) . . . . ?
C1 Pt1 Pt2 P4 -53.8(2) . . . . ?
C3 Pt1 Pt2 P4 -155.49(19) . . . . ?
C2 Pt1 Pt2 P4 36.20(15) . . . . ?
Rh1 Pt1 Pt2 P4 81.31(4) . . . . ?
Rh2 Pt1 Pt2 P4 156.63(4) . . . . ?
C1 Pt1 Pt2 Rh1 -135.1(2) . . . . ?
C3 Pt1 Pt2 Rh1 123.20(19) . . . . ?
C2 Pt1 Pt2 Rh1 -45.12(15) . . . . ?
Rh2 Pt1 Pt2 Rh1 75.320(16) . . . . ?
C1 Pt1 Pt2 Rh2 149.5(2) . . . . ?
C3 Pt1 Pt2 Rh2 47.88(19) . . . . ?
C2 Pt1 Pt2 Rh2 -120.44(15) . . . . ?
Rh1 Pt1 Pt2 Rh2 -75.320(16) . . . . ?
C4 Pt2 Rh1 C2 118.2(6) . . . . ?
P4 Pt2 Rh1 C2 -64.22(14) . . . . ?
Rh2 Pt2 Rh1 C2 114.84(14) . . . . ?
Pt1 Pt2 Rh1 C2 47.81(14) . . . . ?
C4 Pt2 Rh1 C5 -53.4(6) . . . . ?
P4 Pt2 Rh1 C5 124.20(16) . . . . ?
Rh2 Pt2 Rh1 C5 -56.74(15) . . . . ?
Pt1 Pt2 Rh1 C5 -123.77(15) . . . . ?
C4 Pt2 Rh1 P3 -150.1(6) . . . . ?
P4 Pt2 Rh1 P3 27.52(5) . . . . ?
Rh2 Pt2 Rh1 P3 -153.42(4) . . . . ?
Pt1 Pt2 Rh1 P3 139.55(4) . . . . ?
C4 Pt2 Rh1 P1 2.7(6) . . . . ?
P4 Pt2 Rh1 P1 -179.64(11) . . . . ?
Rh2 Pt2 Rh1 P1 -0.58(10) . . . . ?
Pt1 Pt2 Rh1 P1 -67.61(10) . . . . ?
C4 Pt2 Rh1 Pt1 70.4(6) . . . . ?
P4 Pt2 Rh1 Pt1 -112.03(4) . . . . ?
Rh2 Pt2 Rh1 Pt1 67.032(14) . . . . ?
C4 Pt2 Rh1 Rh2 3.3(6) . . . . ?
P4 Pt2 Rh1 Rh2 -179.06(4) . . . . ?
Pt1 Pt2 Rh1 Rh2 -67.032(14) . . . . ?
C1 Pt1 Rh1 C2 7.2(3) . . . . ?
C3 Pt1 Rh1 C2 -170.3(2) . . . . ?
Rh2 Pt1 Rh1 C2 -176.16(17) . . . . ?
Pt2 Pt1 Rh1 C2 -109.94(17) . . . . ?
C1 Pt1 Rh1 C5 174.6(3) . . . . ?
C3 Pt1 Rh1 C5 -2.8(2) . . . . ?
C2 Pt1 Rh1 C5 167.5(2) . . . . ?
Rh2 Pt1 Rh1 C5 -8.71(15) . . . . ?
Pt2 Pt1 Rh1 C5 57.52(15) . . . . ?
C1 Pt1 Rh1 P3 46.7(3) . . . . ?
C3 Pt1 Rh1 P3 -130.77(17) . . . . ?
C2 Pt1 Rh1 P3 39.53(18) . . . . ?
Rh2 Pt1 Rh1 P3 -136.63(5) . . . . ?
Pt2 Pt1 Rh1 P3 -70.41(5) . . . . ?
C1 Pt1 Rh1 P1 -87.1(3) . . . . ?
C3 Pt1 Rh1 P1 95.44(17) . . . . ?
C2 Pt1 Rh1 P1 -94.27(17) . . . . ?
Rh2 Pt1 Rh1 P1 89.57(4) . . . . ?
Pt2 Pt1 Rh1 P1 155.80(4) . . . . ?
C1 Pt1 Rh1 Pt2 117.1(3) . . . . ?
C3 Pt1 Rh1 Pt2 -60.36(17) . . . . ?
C2 Pt1 Rh1 Pt2 109.94(17) . . . . ?
Rh2 Pt1 Rh1 Pt2 -66.222(12) . . . . ?
C1 Pt1 Rh1 Rh2 -176.7(3) . . . . ?
C3 Pt1 Rh1 Rh2 5.86(17) . . . . ?
C2 Pt1 Rh1 Rh2 176.16(17) . . . . ?
Pt2 Pt1 Rh1 Rh2 66.222(12) . . . . ?
C4 Pt2 Rh2 C6 -33.5(3) . . . . ?
P4 Pt2 Rh2 C6 147.7(2) . . . . ?
Rh1 Pt2 Rh2 C6 145.4(2) . . . . ?
Pt1 Pt2 Rh2 C6 -147.9(2) . . . . ?
C4 Pt2 Rh2 C3 67.5(2) . . . . ?
P4 Pt2 Rh2 C3 -111.33(18) . . . . ?
Rh1 Pt2 Rh2 C3 -113.60(16) . . . . ?
Pt1 Pt2 Rh2 C3 -46.89(16) . . . . ?
C4 Pt2 Rh2 C5 -125.7(2) . . . . ?
P4 Pt2 Rh2 C5 55.45(18) . . . . ?
Rh1 Pt2 Rh2 C5 53.18(16) . . . . ?
Pt1 Pt2 Rh2 C5 119.89(16) . . . . ?
C4 Pt2 Rh2 P2 172.1(2) . . . . ?
P4 Pt2 Rh2 P2 -6.74(15) . . . . ?
Rh1 Pt2 Rh2 P2 -9.01(11) . . . . ?
Pt1 Pt2 Rh2 P2 57.71(11) . . . . ?
C4 Pt2 Rh2 Rh1 -178.89(19) . . . . ?
P4 Pt2 Rh2 Rh1 2.27(9) . . . . ?
Pt1 Pt2 Rh2 Rh1 66.715(13) . . . . ?
C4 Pt2 Rh2 Pt1 114.39(19) . . . . ?
P4 Pt2 Rh2 Pt1 -64.44(9) . . . . ?
Rh1 Pt2 Rh2 Pt1 -66.715(13) . . . . ?
C2 Rh1 Rh2 C6 -146.3(3) . . . . ?
C5 Rh1 Rh2 C6 20.2(4) . . . . ?
P3 Rh1 Rh2 C6 -20.5(3) . . . . ?
P1 Rh1 Rh2 C6 112.0(3) . . . . ?
Pt2 Rh1 Rh2 C6 -67.7(3) . . . . ?
Pt1 Rh1 Rh2 C6 -149.6(3) . . . . ?
C2 Rh1 Rh2 C3 -2.6(2) . . . . ?
C5 Rh1 Rh2 C3 163.9(2) . . . . ?
P3 Rh1 Rh2 C3 123.20(17) . . . . ?
P1 Rh1 Rh2 C3 -104.31(17) . . . . ?
Pt2 Rh1 Rh2 C3 75.95(16) . . . . ?
Pt1 Rh1 Rh2 C3 -5.88(16) . . . . ?
C2 Rh1 Rh2 C5 -166.5(2) . . . . ?
P3 Rh1 Rh2 C5 -40.65(19) . . . . ?
P1 Rh1 Rh2 C5 91.84(18) . . . . ?
Pt2 Rh1 Rh2 C5 -87.90(18) . . . . ?
Pt1 Rh1 Rh2 C5 -169.73(18) . . . . ?
C2 Rh1 Rh2 P2 97.58(15) . . . . ?
C5 Rh1 Rh2 P2 -95.96(19) . . . . ?
P3 Rh1 Rh2 P2 -136.61(8) . . . . ?
P1 Rh1 Rh2 P2 -4.12(6) . . . . ?
Pt2 Rh1 Rh2 P2 176.14(5) . . . . ?
Pt1 Rh1 Rh2 P2 94.31(5) . . . . ?
C2 Rh1 Rh2 Pt2 -78.56(14) . . . . ?
C5 Rh1 Rh2 Pt2 87.90(18) . . . . ?
P3 Rh1 Rh2 Pt2 47.25(6) . . . . ?
P1 Rh1 Rh2 Pt2 179.75(4) . . . . ?
Pt1 Rh1 Rh2 Pt2 -81.829(13) . . . . ?
C2 Rh1 Rh2 Pt1 3.27(14) . . . . ?
C5 Rh1 Rh2 Pt1 169.73(18) . . . . ?
P3 Rh1 Rh2 Pt1 129.08(6) . . . . ?
P1 Rh1 Rh2 Pt1 -98.43(4) . . . . ?
Pt2 Rh1 Rh2 Pt1 81.829(13) . . . . ?
C1 Pt1 Rh2 C6 -39.6(5) . . . . ?
C3 Pt1 Rh2 C6 -27.7(4) . . . . ?
C2 Pt1 Rh2 C6 142.0(3) . . . . ?
Rh1 Pt1 Rh2 C6 145.0(3) . . . . ?
Pt2 Pt1 Rh2 C6 79.3(3) . . . . ?
C1 Pt1 Rh2 C3 -11.9(5) . . . . ?
C2 Pt1 Rh2 C3 169.7(2) . . . . ?
Rh1 Pt1 Rh2 C3 172.7(2) . . . . ?
Pt2 Pt1 Rh2 C3 107.0(2) . . . . ?
C1 Pt1 Rh2 C5 -176.6(4) . . . . ?
C3 Pt1 Rh2 C5 -164.7(2) . . . . ?
C2 Pt1 Rh2 C5 5.02(19) . . . . ?
Rh1 Pt1 Rh2 C5 8.00(14) . . . . ?
Pt2 Pt1 Rh2 C5 -57.69(14) . . . . ?
C1 Pt1 Rh2 P2 82.5(4) . . . . ?
C3 Pt1 Rh2 P2 94.3(2) . . . . ?
C2 Pt1 Rh2 P2 -95.94(14) . . . . ?
Rh1 Pt1 Rh2 P2 -92.96(4) . . . . ?
Pt2 Pt1 Rh2 P2 -158.66(4) . . . . ?
C1 Pt1 Rh2 Pt2 -118.9(4) . . . . ?
C3 Pt1 Rh2 Pt2 -107.0(2) . . . . ?
C2 Pt1 Rh2 Pt2 62.71(13) . . . . ?
Rh1 Pt1 Rh2 Pt2 65.693(12) . . . . ?
C1 Pt1 Rh2 Rh1 175.4(4) . . . . ?
C3 Pt1 Rh2 Rh1 -172.7(2) . . . . ?
C2 Pt1 Rh2 Rh1 -2.98(13) . . . . ?
Pt2 Pt1 Rh2 Rh1 -65.693(12) . . . . ?
C2 Rh1 P1 C26 153.6(3) . . . . ?
C5 Rh1 P1 C26 -40.8(3) . . . . ?
P3 Rh1 P1 C26 58.3(2) . . . . ?
Pt2 Rh1 P1 C26 -92.5(2) . . . . ?
Pt1 Rh1 P1 C26 -153.7(2) . . . . ?
Rh2 Rh1 P1 C26 -93.0(2) . . . . ?
C2 Rh1 P1 C8 25.9(3) . . . . ?
C5 Rh1 P1 C8 -168.5(3) . . . . ?
P3 Rh1 P1 C8 -69.4(2) . . . . ?
Pt2 Rh1 P1 C8 139.8(2) . . . . ?
Pt1 Rh1 P1 C8 78.6(2) . . . . ?
Rh2 Rh1 P1 C8 139.2(2) . . . . ?
C2 Rh1 P1 C7 -87.1(3) . . . . ?
C5 Rh1 P1 C7 78.4(3) . . . . ?
P3 Rh1 P1 C7 177.6(2) . . . . ?
Pt2 Rh1 P1 C7 26.7(3) . . . . ?
Pt1 Rh1 P1 C7 -34.4(2) . . . . ?
Rh2 Rh1 P1 C7 26.2(2) . . . . ?
C6 Rh2 P2 C14 78.7(3) . . . . ?
C3 Rh2 P2 C14 -24.1(3) . . . . ?
C5 Rh2 P2 C14 177.1(3) . . . . ?
Pt2 Rh2 P2 C14 -126.6(2) . . . . ?
Rh1 Rh2 P2 C14 -134.4(2) . . . . ?
Pt1 Rh2 P2 C14 -74.2(2) . . . . ?
C6 Rh2 P2 C20 -47.2(3) . . . . ?
C3 Rh2 P2 C20 -150.0(3) . . . . ?
C5 Rh2 P2 C20 51.2(3) . . . . ?
Pt2 Rh2 P2 C20 107.4(3) . . . . ?
Rh1 Rh2 P2 C20 99.7(2) . . . . ?
Pt1 Rh2 P2 C20 159.9(2) . . . . ?
C6 Rh2 P2 C7 -165.6(3) . . . . ?
C3 Rh2 P2 C7 91.6(3) . . . . ?
C5 Rh2 P2 C7 -67.2(3) . . . . ?
Pt2 Rh2 P2 C7 -11.0(3) . . . . ?
Rh1 Rh2 P2 C7 -18.7(2) . . . . ?
Pt1 Rh2 P2 C7 41.5(2) . . . . ?
C2 Rh1 P3 C51 172.1(2) . . . . ?
C5 Rh1 P3 C51 9.6(2) . . . . ?
P1 Rh1 P3 C51 -87.5(2) . . . . ?
Pt2 Rh1 P3 C51 80.23(19) . . . . ?
Pt1 Rh1 P3 C51 142.04(19) . . . . ?
Rh2 Rh1 P3 C51 40.8(2) . . . . ?
C2 Rh1 P3 C45 -59.4(2) . . . . ?
C5 Rh1 P3 C45 138.1(2) . . . . ?
P1 Rh1 P3 C45 41.0(2) . . . . ?
Pt2 Rh1 P3 C45 -151.3(2) . . . . ?
Pt1 Rh1 P3 C45 -89.5(2) . . . . ?
Rh2 Rh1 P3 C45 169.28(19) . . . . ?
C2 Rh1 P3 C32 53.5(2) . . . . ?
C5 Rh1 P3 C32 -109.0(2) . . . . ?
P1 Rh1 P3 C32 153.93(18) . . . . ?
Pt2 Rh1 P3 C32 -38.38(18) . . . . ?
Pt1 Rh1 P3 C32 23.4(2) . . . . ?
Rh2 Rh1 P3 C32 -77.82(19) . . . . ?
C4 Pt2 P4 C39 -80.0(3) . . . . ?
Rh1 Pt2 P4 C39 100.83(17) . . . . ?
Rh2 Pt2 P4 C39 98.83(19) . . . . ?
Pt1 Pt2 P4 C39 45.24(18) . . . . ?
C4 Pt2 P4 C33 40.2(3) . . . . ?
Rh1 Pt2 P4 C33 -139.0(2) . . . . ?
Rh2 Pt2 P4 C33 -141.0(2) . . . . ?
Pt1 Pt2 P4 C33 165.5(2) . . . . ?
C4 Pt2 P4 C32 164.7(3) . . . . ?
Rh1 Pt2 P4 C32 -14.48(19) . . . . ?
Rh2 Pt2 P4 C32 -16.5(2) . . . . ?
Pt1 Pt2 P4 C32 -70.07(19) . . . . ?
C3 Pt1 C1 O1 162(7) . . . . ?
C2 Pt1 C1 O1 -10(8) . . . . ?
Rh1 Pt1 C1 O1 -16(8) . . . . ?
Rh2 Pt1 C1 O1 171(7) . . . . ?
Pt2 Pt1 C1 O1 72(8) . . . . ?
C5 Rh1 C2 O2 136.7(7) . . . . ?
P3 Rh1 C2 O2 19.8(7) . . . . ?
P1 Rh1 C2 O2 -91.3(7) . . . . ?
Pt2 Rh1 C2 O2 112.3(7) . . . . ?
Pt1 Rh1 C2 O2 173.8(8) . . . . ?
Rh2 Rh1 C2 O2 170.2(7) . . . . ?
C5 Rh1 C2 Pt1 -37.1(6) . . . . ?
P3 Rh1 C2 Pt1 -154.01(11) . . . . ?
P1 Rh1 C2 Pt1 94.88(11) . . . . ?
Pt2 Rh1 C2 Pt1 -61.54(11) . . . . ?
Rh2 Rh1 C2 Pt1 -3.61(16) . . . . ?
C1 Pt1 C2 O2 9.0(6) . . . . ?
C3 Pt1 C2 O2 -152.7(5) . . . . ?
Rh1 Pt1 C2 O2 -175.2(6) . . . . ?
Rh2 Pt1 C2 O2 -171.7(5) . . . . ?
Pt2 Pt1 C2 O2 -124.1(5) . . . . ?
C1 Pt1 C2 Rh1 -175.8(2) . . . . ?
C3 Pt1 C2 Rh1 22.5(6) . . . . ?
Rh2 Pt1 C2 Rh1 3.48(16) . . . . ?
Pt2 Pt1 C2 Rh1 51.15(10) . . . . ?
C6 Rh2 C3 O3 -9.4(8) . . . . ?
C5 Rh2 C3 O3 -140.5(7) . . . . ?
P2 Rh2 C3 O3 92.8(7) . . . . ?
Pt2 Rh2 C3 O3 -111.9(7) . . . . ?
Rh1 Rh2 C3 O3 -168.2(7) . . . . ?
Pt1 Rh2 C3 O3 -174.9(8) . . . . ?
C6 Rh2 C3 Pt1 165.49(19) . . . . ?
C5 Rh2 C3 Pt1 34.4(5) . . . . ?
P2 Rh2 C3 Pt1 -92.34(14) . . . . ?
Pt2 Rh2 C3 Pt1 62.98(13) . . . . ?
Rh1 Rh2 C3 Pt1 6.66(18) . . . . ?
C1 Pt1 C3 O3 -10.2(8) . . . . ?
C2 Pt1 C3 O3 150.8(6) . . . . ?
Rh1 Pt1 C3 O3 168.3(7) . . . . ?
Rh2 Pt1 C3 O3 174.9(8) . . . . ?
Pt2 Pt1 C3 O3 122.1(7) . . . . ?
C1 Pt1 C3 Rh2 174.8(2) . . . . ?
C2 Pt1 C3 Rh2 -24.2(6) . . . . ?
Rh1 Pt1 C3 Rh2 -6.66(19) . . . . ?
Pt2 Pt1 C3 Rh2 -52.80(11) . . . . ?
P4 Pt2 C4 O4 78(29) . . . . ?
Rh1 Pt2 C4 O4 -104(28) . . . . ?
Rh2 Pt2 C4 O4 -101(29) . . . . ?
Pt1 Pt2 C4 O4 -44(29) . . . . ?
C2 Rh1 C5 O5 -140.5(7) . . . . ?
P3 Rh1 C5 O5 -24.5(8) . . . . ?
P1 Rh1 C5 O5 86.9(7) . . . . ?
Pt2 Rh1 C5 O5 -114.5(8) . . . . ?
Pt1 Rh1 C5 O5 -171.3(7) . . . . ?
Rh2 Rh1 C5 O5 179.1(8) . . . . ?
C2 Rh1 C5 Rh2 40.4(6) . . . . ?
P3 Rh1 C5 Rh2 156.45(10) . . . . ?
P1 Rh1 C5 Rh2 -92.25(12) . . . . ?
Pt2 Rh1 C5 Rh2 66.39(11) . . . . ?
Pt1 Rh1 C5 Rh2 9.61(17) . . . . ?
C6 Rh2 C5 O5 12.7(6) . . . . ?
C3 Rh2 C5 O5 144.5(5) . . . . ?
P2 Rh2 C5 O5 -88.8(5) . . . . ?
Pt2 Rh2 C5 O5 113.6(6) . . . . ?
Rh1 Rh2 C5 O5 -179.3(6) . . . . ?
Pt1 Rh2 C5 O5 171.4(5) . . . . ?
C6 Rh2 C5 Rh1 -168.0(2) . . . . ?
C3 Rh2 C5 Rh1 -36.2(5) . . . . ?
P2 Rh2 C5 Rh1 90.46(13) . . . . ?
Pt2 Rh2 C5 Rh1 -67.07(12) . . . . ?
Pt1 Rh2 C5 Rh1 -9.29(16) . . . . ?
C3 Rh2 C6 O6 -162(13) . . . . ?
C5 Rh2 C6 O6 -2(13) . . . . ?
P2 Rh2 C6 O6 98(13) . . . . ?
Pt2 Rh2 C6 O6 -71(13) . . . . ?
Rh1 Rh2 C6 O6 -17(13) . . . . ?
Pt1 Rh2 C6 O6 -141(13) . . . . ?
C14 P2 C7 P1 165.5(4) . . . . ?
C20 P2 C7 P1 -87.8(4) . . . . ?
Rh2 P2 C7 P1 42.5(4) . . . . ?
C26 P1 C7 P2 81.6(4) . . . . ?
C8 P1 C7 P2 -172.4(3) . . . . ?
Rh1 P1 C7 P2 -46.1(4) . . . . ?
C26 P1 C8 C9 167.5(4) . . . . ?
C7 P1 C8 C9 60.2(5) . . . . ?
Rh1 P1 C8 C9 -57.9(5) . . . . ?
C26 P1 C8 C13 -15.2(5) . . . . ?
C7 P1 C8 C13 -122.6(5) . . . . ?
Rh1 P1 C8 C13 119.4(4) . . . . ?
C13 C8 C9 C10 1.6(8) . . . . ?
P1 C8 C9 C10 179.0(4) . . . . ?
C8 C9 C10 C11 -1.7(8) . . . . ?
C9 C10 C11 C12 0.6(9) . . . . ?
C10 C11 C12 C13 0.5(9) . . . . ?
C11 C12 C13 C8 -0.6(8) . . . . ?
C9 C8 C13 C12 -0.4(8) . . . . ?
P1 C8 C13 C12 -177.7(4) . . . . ?
C20 P2 C14 C19 88.0(7) . . . . ?
C7 P2 C14 C19 -166.6(7) . . . . ?
Rh2 P2 C14 C19 -47.0(7) . . . . ?
C20 P2 C14 C15 -90.0(6) . . . . ?
C7 P2 C14 C15 15.4(7) . . . . ?
Rh2 P2 C14 C15 135.0(5) . . . . ?
C19 C14 C15 C16 -0.6(11) . . . . ?
P2 C14 C15 C16 177.4(6) . . . . ?
C14 C15 C16 C17 1.3(13) . . . . ?
C15 C16 C17 C18 -0.5(16) . . . . ?
C16 C17 C18 C19 -0.9(19) . . . . ?
C17 C18 C19 C14 1.6(19) . . . . ?
C15 C14 C19 C18 -0.9(15) . . . . ?
P2 C14 C19 C18 -178.9(9) . . . . ?
C14 P2 C20 C25 -152.3(5) . . . . ?
C7 P2 C20 C25 101.2(5) . . . . ?
Rh2 P2 C20 C25 -21.2(6) . . . . ?
C14 P2 C20 C21 33.7(6) . . . . ?
C7 P2 C20 C21 -72.9(6) . . . . ?
Rh2 P2 C20 C21 164.7(5) . . . . ?
C25 C20 C21 C22 -0.7(11) . . . . ?
P2 C20 C21 C22 173.6(6) . . . . ?
C20 C21 C22 C23 -0.9(13) . . . . ?
C21 C22 C23 C24 1.4(12) . . . . ?
C22 C23 C24 C25 -0.3(11) . . . . ?
C21 C20 C25 C24 1.8(10) . . . . ?
P2 C20 C25 C24 -172.5(5) . . . . ?
C23 C24 C25 C20 -1.3(10) . . . . ?
C8 P1 C26 C31 117.0(5) . . . . ?
C7 P1 C26 C31 -139.9(4) . . . . ?
Rh1 P1 C26 C31 -18.4(5) . . . . ?
C8 P1 C26 C27 -62.0(5) . . . . ?
C7 P1 C26 C27 41.1(5) . . . . ?
Rh1 P1 C26 C27 162.6(4) . . . . ?
C31 C26 C27 C28 -0.3(9) . . . . ?
P1 C26 C27 C28 178.7(5) . . . . ?
C26 C27 C28 C29 0.4(10) . . . . ?
C27 C28 C29 C30 -0.7(10) . . . . ?
C28 C29 C30 C31 0.9(10) . . . . ?
C29 C30 C31 C26 -0.8(10) . . . . ?
C27 C26 C31 C30 0.5(9) . . . . ?
P1 C26 C31 C30 -178.5(5) . . . . ?
C39 P4 C32 P3 -132.9(3) . . . . ?
C33 P4 C32 P3 118.7(3) . . . . ?
Pt2 P4 C32 P3 -10.5(3) . . . . ?
C51 P3 C32 P4 -91.2(3) . . . . ?
C45 P3 C32 P4 162.8(3) . . . . ?
Rh1 P3 C32 P4 35.3(3) . . . . ?
C39 P4 C33 C34 -125.6(5) . . . . ?
C32 P4 C33 C34 -18.8(5) . . . . ?
Pt2 P4 C33 C34 109.0(4) . . . . ?
C39 P4 C33 C38 58.7(4) . . . . ?
C32 P4 C33 C38 165.5(4) . . . . ?
Pt2 P4 C33 C38 -66.8(4) . . . . ?
C38 C33 C34 C35 0.3(8) . . . . ?
P4 C33 C34 C35 -175.4(4) . . . . ?
C33 C34 C35 C36 -1.2(9) . . . . ?
C34 C35 C36 C37 0.6(9) . . . . ?
C35 C36 C37 C38 1.1(9) . . . . ?
C36 C37 C38 C33 -2.1(8) . . . . ?
C34 C33 C38 C37 1.4(8) . . . . ?
P4 C33 C38 C37 177.3(4) . . . . ?
C33 P4 C39 C44 -136.6(4) . . . . ?
C32 P4 C39 C44 112.5(4) . . . . ?
Pt2 P4 C39 C44 -9.8(5) . . . . ?
C33 P4 C39 C40 49.4(5) . . . . ?
C32 P4 C39 C40 -61.5(4) . . . . ?
Pt2 P4 C39 C40 176.2(4) . . . . ?
C44 C39 C40 C41 -0.1(8) . . . . ?
P4 C39 C40 C41 174.0(4) . . . . ?
C39 C40 C41 C42 -0.2(8) . . . . ?
C40 C41 C42 C43 0.1(8) . . . . ?
C41 C42 C43 C44 0.2(8) . . . . ?
C40 C39 C44 C43 0.4(8) . . . . ?
P4 C39 C44 C43 -173.6(4) . . . . ?
C42 C43 C44 C39 -0.5(8) . . . . ?
C51 P3 C45 C50 132.9(4) . . . . ?
C32 P3 C45 C50 -120.7(4) . . . . ?
Rh1 P3 C45 C50 -1.5(5) . . . . ?
C51 P3 C45 C46 -52.0(5) . . . . ?
C32 P3 C45 C46 54.5(5) . . . . ?
Rh1 P3 C45 C46 173.6(4) . . . . ?
C50 C45 C46 C47 0.7(8) . . . . ?
P3 C45 C46 C47 -174.4(4) . . . . ?
C45 C46 C47 C48 -0.6(8) . . . . ?
C46 C47 C48 C49 -0.3(8) . . . . ?
C47 C48 C49 C50 1.0(8) . . . . ?
C46 C45 C50 C49 0.0(8) . . . . ?
P3 C45 C50 C49 175.2(4) . . . . ?
C48 C49 C50 C45 -0.9(8) . . . . ?
C45 P3 C51 C52 -25.0(5) . . . . ?
C32 P3 C51 C52 -126.6(4) . . . . ?
Rh1 P3 C51 C52 111.6(4) . . . . ?
C45 P3 C51 C56 158.9(4) . . . . ?
C32 P3 C51 C56 57.3(4) . . . . ?
Rh1 P3 C51 C56 -64.5(4) . . . . ?
C56 C51 C52 C53 0.2(7) . . . . ?
P3 C51 C52 C53 -175.9(4) . . . . ?
C51 C52 C53 C54 -1.4(8) . . . . ?
C52 C53 C54 C55 1.1(8) . . . . ?
C53 C54 C55 C56 0.4(8) . . . . ?
C54 C55 C56 C51 -1.6(7) . . . . ?
C52 C51 C56 C55 1.3(7) . . . . ?
P3 C51 C56 C55 177.5(4) . . . . ?
loop_
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1 PubChem 139154606
