Information card for entry 7011508

Structure parameters

• Formula: C24 H38 Cl F6 Ir2 P S3
• Calculated formula: C24 H38 Cl F6 Ir2 P S3
• Title of publication: Nucleophilic addition and substitution reactions on the sulfur atoms bound to two Ir atoms. Conversion of a hydrosulfido complex [(??5-C5Me5)2Ir2(??-SH)3]Cl into a series of diiridium complexes with bridging thiolato ligands
• Authors of publication: Takagi, Fusao; Seino, Hidetake; Hidai, Masanobu; Mizobe, Yasushi
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 18
• Pages of publication: 3603
• a: 11.039 ± 0.002 Å
• b: 11.287 ± 0.001 Å
• c: 12.663 ± 0.003 Å
• α: 92.26 ± 0.01°
• β: 95.68 ± 0.02°
• γ: 100.85 ± 0.01°
• Cell volume: 1539.2 ± 0.5 ų
• Cell temperature: 296.2 K
• Ambient diffraction temperature: 296.2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0302
• Residual factor for significantly intense reflections: 0.0302
• Weighted residual factors for significantly intense reflections: 0.0307
• Weighted residual factors for all reflections included in the refinement: 0.0307
• Goodness-of-fit parameter for all reflections included in the refinement: 1.545
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No