Information card for entry 7012905

Structure parameters

• Chemical name: trans-mu-dichloro(cyclooctene)diplatinum(II)
• Formula: C16 H28 Cl4 Pt2
• Calculated formula: C16 H28 Cl4 Pt2
• SMILES: [CH]12=[CH](CCCCCC2)[Pt]21([Cl][Pt]1([CH]3=[CH]1CCCCCC3)([Cl]2)Cl)Cl
• Title of publication: Bridge-splitting kinetics, equilibria and structures of trans-biscyclooctene complexes of platinum(ii)Electronic supplementary information (ESI) available: observed pseudo-first order rate constants for bridge splitting reactions, absorbance versus added ligand concentrations for equlibrium constant determinations and complete crystallographic details in CIF format. See http://www.rsc.org/suppdata/dt/b3/b302482m/
• Authors of publication: Otto, Stefanus; Roodt, Andreas; Elding, Lars I.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 12
• Pages of publication: 2519
• a: 8.231 ± 0.0016 Å
• b: 5.96 ± 0.0012 Å
• c: 20.991 ± 0.004 Å
• α: 90°
• β: 99.68 ± 0.03°
• γ: 90°
• Cell volume: 1015.1 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0734
• Residual factor for significantly intense reflections: 0.065
• Weighted residual factors for significantly intense reflections: 0.1622
• Weighted residual factors for all reflections included in the refinement: 0.1668
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No