Information card for entry 7012921

Structure parameters

• Formula: C30 H74 K2 O8 Si4 Zn2
• Calculated formula: C30 H74 K2 O8 Si4 Zn2
• SMILES: [Zn]12([O]3([K]4([O]5([Zn]3([O]1([K]5([O]24[Si](C)(C)C)([O]1CCCC1)[O]1CCCC1)[Si](C)(C)C)C)[Si](C)(C)C)([O]1CCCC1)[O]1CCCC1)[Si](C)(C)C)C
• Title of publication: Facile synthesis and structural variation of novel heterobimetallic alkali metal?zinc-alkoxide and -siloxide clustersElectronic supplementary information (ESI) available: the ESI spectra of the reaction mixtures tBuOLi + ZnMe2, Me3SiOK + ZnMe2 and tBuOK + ZnMe2. See http://www.rsc.org/suppdata/dt/b3/b302585c/
• Authors of publication: Merz, Klaus; Block, Stefan; Schoenen, Robert; Driess, Matthias
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 17
• Pages of publication: 3365
• a: 24.379 ± 0.004 Å
• b: 13.394 ± 0.003 Å
• c: 15.094 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4928.7 ± 1.7 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0754
• Residual factor for significantly intense reflections: 0.0446
• Weighted residual factors for significantly intense reflections: 0.0944
• Weighted residual factors for all reflections included in the refinement: 0.1095
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No