Information card for entry 7012950

Structure parameters

• Chemical name: [Bis(1,2-(diphenylphosphino)ethane)palladium(II)]- di(chloro-1-carbadodecaboranyl)-tris methylene chloride
• Formula: C57 H75 B22 Cl8 P4 Pd
• Calculated formula: C57 H75.04 B22 Cl8 P4 Pd
• Title of publication: Dihalogeno(diphosphane)metal(II) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene – elucidation of the activation process with B(C6F5)3/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of “naked” Pd2+ as a highly active species
• Authors of publication: Lassahn, Paul-Gerhard; Lozan, Vasile; Wu, Biao; Weller, Andrew S.; Janiak, Christoph
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 23
• Pages of publication: 4437 - 4450
• a: 19.75 ± 0.0015 Å
• b: 16.0288 ± 0.0012 Å
• c: 13.7704 ± 0.0011 Å
• α: 90°
• β: 119.159 ± 0.001°
• γ: 90°
• Cell volume: 3806.8 ± 0.5 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 6
• Space group number: 12
• Hermann-Mauguin space group symbol: C 1 2/m 1
• Hall space group symbol: -C 2y
• Residual factor for all reflections: 0.0549
• Residual factor for significantly intense reflections: 0.0418
• Weighted residual factors for significantly intense reflections: 0.1181
• Weighted residual factors for all reflections included in the refinement: 0.1274
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No