Information card for entry 7013231

Structure parameters

• Chemical name: [Pt2Cl4(2,3-trans-dppcbSe2-P,P',Se,Se')]
• Formula: C94.5 H104.5 Cl6 N5.5 O5.5 P6 Pt3 Se2
• Calculated formula: C94.5 H101 Cl6 N5.5 O5.5 P6 Pt3 Se2
• Title of publication: Regioselective versus complete chalcogen transfer reactions of the bis(bidentate) phosphine cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane: full characterization of new, hemilabile ligands and their complexes with palladium(II) and platinum(II)
• Authors of publication: Thomas Stampfl; Rene Gutmann; Georg Czermak; Christoph Langes; Alexander Dumfort; Holger Kopacka; Karl-Hans Ongania; Peter Brüggeller
• Journal of publication: Dalton Trans.
• Year of publication: 2003
• Journal issue: 17
• Pages of publication: 3425 - 3435
• a: 14.9398 ± 0.0005 Å
• b: 18.8634 ± 0.0006 Å
• c: 19.2668 ± 0.0006 Å
• α: 68.799 ± 0.002°
• β: 80.929 ± 0.002°
• γ: 87.253 ± 0.002°
• Cell volume: 4998.6 ± 0.3 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0645
• Residual factor for significantly intense reflections: 0.0355
• Weighted residual factors for significantly intense reflections: 0.078
• Weighted residual factors for all reflections included in the refinement: 0.0891
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No