Information card for entry 7013287

Structure parameters

• Formula: C56 H44 Cl4 Co2 O5 P4 Pd
• Calculated formula: C56 H44 Cl4 Co2 O5 P4 Pd
• SMILES: [Pd]123([Co]456([Co]7([P](c8ccccc8)(c8ccccc8)C[P]4(c4ccccc4)c4ccccc4)([C]5([P](=O)(c4ccccc4)c4ccccc4)=[C]67[P]1(c1ccccc1)c1ccccc1)(C#[O])C#[O])(C2=O)C3=O)(Cl)Cl.C(Cl)Cl
• Title of publication: Synthesis and structural characterization of novel palladium complexes chelated by bulky cobalt-containing phosphine ligands: unusual palladium?cobalt bond formation
• Authors of publication: Hong, Fung-E; Chang, Chin-Pei; Chang, Yu-Chang
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 20
• Pages of publication: 3892
• a: 11.1922 ± 0.0008 Å
• b: 13.1178 ± 0.0009 Å
• c: 19.4159 ± 0.0014 Å
• α: 94.988 ± 0.001°
• β: 100.917 ± 0.002°
• γ: 101.41 ± 0.001°
• Cell volume: 2720.7 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0542
• Residual factor for significantly intense reflections: 0.0385
• Weighted residual factors for significantly intense reflections: 0.0993
• Weighted residual factors for all reflections included in the refinement: 0.1096
• Goodness-of-fit parameter for all reflections included in the refinement: 0.983
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No