The structural and spectroscopic characterisation of three actinyl complexes with coordinated and uncoordinated perrhenate: [UO2(ReO4)2(TPPO)3], [[(UO2)(TPPO)3]2(mu2-O2)][ReO4]2 and [NpO2(TPPO)4][ReO4].
Authors of publication
John, Gordon H.; May, Iain; Sarsfield, Mark J.; Steele, Helen M.; Collison, David; Helliwell, Madeleine; McKinney, James D.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2004
Journal issue
5
Pages of publication
734 - 740
a
10.624 ± 0.002 Å
b
16.507 ± 0.003 Å
c
17.381 ± 0.003 Å
α
66.424 ± 0.01°
β
85.365 ± 0.01°
γ
77.024 ± 0.01°
Cell volume
2722.2 ± 0.9 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
273.2 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0588
Residual factor for significantly intense reflections
0.0495
Weighted residual factors for significantly intense reflections
0.1413
Weighted residual factors for all reflections included in the refinement
0.1482
Goodness-of-fit parameter for all reflections included in the refinement
