Information card for entry 7013959

Structure parameters

• Common name: (Y(CH(SiMe3)2)3(NCtBu)2). 1/2(cyclohexane)
• Formula: C34 H81 N2 Si6 Y
• Calculated formula: C34 H81 N2 Si6 Y
• SMILES: C1CCCCC1.[Y](C([Si](C)(C)C)[Si](C)(C)C)(C([Si](C)(C)C)[Si](C)(C)C)(C([Si](C)(C)C)[Si](C)(C)C)([N]#CC(C)(C)C)[N]#CC(C)(C)C
• Title of publication: Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium beta-diketiminates.
• Authors of publication: Avent, Anthony G.; Caro, Catherine F.; Hitchcock, Peter B.; Lappert, Michael F.; Li, Zhengning; Wei, Xue-Hong
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2004
• Journal issue: 10
• Pages of publication: 1567 - 1577
• a: 12.4967 ± 0.0004 Å
• b: 12.4967 ± 0.0004 Å
• c: 108.85 ± 0.04 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 14721 ± 5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 167
• Hermann-Mauguin space group symbol: R -3 c :H
• Hall space group symbol: -R 3 2"c
• Residual factor for all reflections: 0.0629
• Residual factor for significantly intense reflections: 0.0418
• Weighted residual factors for significantly intense reflections: 0.0873
• Weighted residual factors for all reflections included in the refinement: 0.0939
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No