From the tetra(amino) phosphonium cation, [P(NHPh)4]+, to the tetra(imino) phosphate trianion, [P(NPh)4]3-, two-faced ligands that bind anions and cations.
Authors of publication
Bickley, Jamie F.; Copsey, May C.; Jeffery, John C.; Leedham, Angela P.; Russell, Christopher A.; Stalke, Dietmar; Steiner, Alexander; Stey, Thomas; Zacchini, Stefano
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2004
Journal issue
7
Pages of publication
989 - 995
a
39.229 ± 0.003 Å
b
9.9824 ± 0.0007 Å
c
18.6572 ± 0.0013 Å
α
90°
β
94.512 ± 0.001°
γ
90°
Cell volume
7283.5 ± 0.9 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
6
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0574
Residual factor for significantly intense reflections
0.0485
Weighted residual factors for significantly intense reflections
0.1265
Weighted residual factors for all reflections included in the refinement
0.1324
Goodness-of-fit parameter for all reflections included in the refinement