Information card for entry 7015163

Structure parameters

• Common name: ((mu-bipyridine)bis-((E)-2-((2-aminoethylimino)methyl)4- methoxyphenolato-copper(ii)))diperchlorate
• Chemical name: ((μ-bipyridine)bis-[(E)-2-((2-aminoethylimino)methyl)4-methoxyphenolato- copper(II)])diperchlorate
• Formula: C30 H34 Cl2 Cu2 N6 O12
• Calculated formula: C30 H34 Cl2 Cu2 N6 O12
• SMILES: C1C[N]2[Cu]([NH2]1)([n]1ccc(c3cc[n](cc3)[Cu]34[N](CC[NH2]3)=Cc3cc(ccc3O4)OC)cc1)Oc1c(C=2)cc(cc1)OC.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-]
• Title of publication: Synthesis, crystal structures and magnetic properties of dinuclear copper(II) compounds with NNO tridentate Schiff base ligands and bridging aliphatic diamine and aromatic diimine linkers.
• Authors of publication: Rigamonti, Luca; Forni, Alessandra; Pievo, Roberta; Reedijk, Jan; Pasini, Alessandro
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 13
• Pages of publication: 3381 - 3393
• a: 22.441 ± 0.003 Å
• b: 8.2417 ± 0.001 Å
• c: 19.432 ± 0.002 Å
• α: 90°
• β: 112.963 ± 0.001°
• γ: 90°
• Cell volume: 3309.2 ± 0.7 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0434
• Residual factor for significantly intense reflections: 0.0371
• Weighted residual factors for significantly intense reflections: 0.0995
• Weighted residual factors for all reflections included in the refinement: 0.1047
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No