Information card for entry 7016243

Structure parameters

• Formula: C69 H54 B F24 P2 Rh S
• Calculated formula: C69 H54 B F24 P2 Rh S
• Title of publication: Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)](+) fragment.
• Authors of publication: Dallanegra, Romaeo; Pilgrim, Ben S.; Chaplin, Adrian B.; Donohoe, Timothy J.; Weller, Andrew S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 25
• Pages of publication: 6626 - 6628
• a: 22.6994 ± 0.0002 Å
• b: 17.4801 ± 0.0001 Å
• c: 18.6265 ± 0.0001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7390.77 ± 0.09 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0506
• Residual factor for significantly intense reflections: 0.0421
• Weighted residual factors for significantly intense reflections: 0.1098
• Weighted residual factors for all reflections included in the refinement: 0.116
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No