Donor-stabilised cations, phosphinamide anions, and unusual oxidative cyclisation products from halogenated phosphoranimines and phosphinimines with a bulky 2,4,6-tri-tert-butylphenyl substituent at nitrogen.
Authors of publication
Huynh, Keith; Chun, Cindy P.; Lough, Alan J.; Manners, Ian
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2011
Journal volume
40
Journal issue
40
Pages of publication
10576 - 10584
a
19.0219 ± 0.0007 Å
b
15.6776 ± 0.0008 Å
c
6.1422 ± 0.0003 Å
α
90°
β
90°
γ
90°
Cell volume
1831.71 ± 0.15 Å3
Cell temperature
150 ± 1 K
Ambient diffraction temperature
150 ± 1 K
Number of distinct elements
5
Space group number
62
Hermann-Mauguin space group symbol
P n m a
Hall space group symbol
-P 2ac 2n
Residual factor for all reflections
0.0713
Residual factor for significantly intense reflections
0.0472
Weighted residual factors for significantly intense reflections
0.1141
Weighted residual factors for all reflections included in the refinement
0.1288
Goodness-of-fit parameter for all reflections included in the refinement
