Information card for entry 7016903

Structure parameters

• Common name: cis-chlorido(4-tert-butyl)pyridinebis (triphenylphosphane)platinum(ii) tetrafluoborate
• Chemical name: cis-chlorido(4-tert-butyl)pyridinebis (triphenylphosphane)platinum(II) tetrafluoborate
• Formula: C45 H43 B Cl F4 N P2 Pt
• Calculated formula: C45 H43 B Cl F4 N P2 Pt
• Title of publication: The role of the atomic charges on the ligands and platinum(ii) in affecting the cis and trans influences in [PtXL(PPh(3))(2)](+) complexes (X = NO(3), Cl, Br, I; L = 4-substituted pyridines, amines, PPh(3)). A (31)P NMR and DFT investigation.
• Authors of publication: Rigamonti, Luca; Rusconi, Michele; Forni, Alessandra; Pasini, Alessandro
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 39
• Pages of publication: 10162 - 10173
• a: 18.1703 ± 0.0011 Å
• b: 10.9178 ± 0.0007 Å
• c: 21.1239 ± 0.0013 Å
• α: 90°
• β: 91.105 ± 0.001°
• γ: 90°
• Cell volume: 4189.8 ± 0.5 ų
• Cell temperature: 294 ± 2 K
• Ambient diffraction temperature: 294 ± 2 K
• Number of distinct elements: 8
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0278
• Residual factor for significantly intense reflections: 0.024
• Weighted residual factors for significantly intense reflections: 0.0517
• Weighted residual factors for all reflections included in the refinement: 0.0532
• Goodness-of-fit parameter for all reflections included in the refinement: 0.907
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No