Effects of alkyl chain length and anion size on thermal and structural properties for 1-alkyl-3-methylimidazolium hexafluorocomplex salts (C(x)MImAF(6), x = 14, 16 and 18; A = P, As, Sb, Nb and Ta).
Authors of publication
Xu, Fei; Matsumoto, Kazuhiko; Hagiwara, Rika
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2012
Journal volume
41
Journal issue
12
Pages of publication
3494 - 3502
a
9.5645 ± 0.0013 Å
b
9.862 ± 0.0015 Å
c
28.969 ± 0.004 Å
α
90°
β
94.4 ± 0.003°
γ
90°
Cell volume
2724.5 ± 0.7 Å3
Cell temperature
298 K
Ambient diffraction temperature
298 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/a 1
Hall space group symbol
-P 2yab
Residual factor for all reflections
0.1466
Residual factor for significantly intense reflections
0.0886
Weighted residual factors for significantly intense reflections
0.272
Weighted residual factors for all reflections included in the refinement
0.3324
Goodness-of-fit parameter for all reflections included in the refinement