Information card for entry 7018941

Structure parameters

• Formula: C56 H46 Cl7 P3 Pd3 S3
• Calculated formula: C56 H46 Cl7 P3 Pd3 S3
• SMILES: [Pd]123[S]([Pd]4(Cl)[S]([Pd](Cl)(Cl)[S]1c1c([P]3(c3ccccc3)c3ccccc3)cccc1)c1c([P]4(c3ccccc3)c3ccccc3)cccc1)c1c([P]2(c2ccccc2)c2ccccc2)cccc1.ClCCl.ClCCl
• Title of publication: Reaction of a heterotopic P,SAs ligand with group 10 metal(ii) complexes: As-S bond cleavage and the formation of two unusual trinuclear structural isomers for Pd and Pt.
• Authors of publication: Sárosi, Imola; Hildebrand, Alexandra; Lönnecke, Peter; Silaghi-Dumitrescu, Luminiţa; Hey-Hawkins, Evamarie
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 17
• Pages of publication: 5326 - 5333
• a: 17.0782 ± 0.0004 Å
• b: 11.9468 ± 0.0003 Å
• c: 28.354 ± 0.0007 Å
• α: 90°
• β: 100.312 ± 0.002°
• γ: 90°
• Cell volume: 5691.6 ± 0.2 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1129
• Residual factor for significantly intense reflections: 0.0691
• Weighted residual factors for significantly intense reflections: 0.1048
• Weighted residual factors for all reflections included in the refinement: 0.1182
• Goodness-of-fit parameter for all reflections included in the refinement: 1.08
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No