Synthesis, characterisation and theoretical study of ruthenium 4,4'-bi-1,2,3-triazolyl complexes: fundamental switching of the nature of S(1) and T(1) states from MLCT to MC.
Authors of publication
Welby, Christine E.; Grkinic, Stev; Zahid, Adam; Uppal, Baljinder S.; Gibson, Elizabeth A.; Rice, Craig R.; Elliott, Paul I. P.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2012
Journal volume
41
Journal issue
25
Pages of publication
7637 - 7646
a
17.4573 ± 0.0007 Å
b
15.6748 ± 0.0006 Å
c
16.6134 ± 0.0006 Å
α
90°
β
90°
γ
90°
Cell volume
4546.1 ± 0.3 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
6
Space group number
60
Hermann-Mauguin space group symbol
P b c n
Hall space group symbol
-P 2n 2ab
Residual factor for all reflections
0.0634
Residual factor for significantly intense reflections
0.0452
Weighted residual factors for significantly intense reflections
0.128
Weighted residual factors for all reflections included in the refinement
0.1445
Goodness-of-fit parameter for all reflections included in the refinement
