Information card for entry 7019558

Structure parameters

• Common name: hexa(N,N-dimethyl-N'-(2,3,5,6- tetrafluorophenyl)ethylenediamine-F,N,N') -tris-fluoro-triscerium(iii) toluene solvate
• Chemical name: hexa(N,N-dimethyl-N'-(2,3,5,6-tetrafluorophenyl)ethylenediamine-F,N,N') -tris-fluoro-triscerium(iii) toluene solvate
• Formula: C70.5 H78 Ce3 F27 N12
• Calculated formula: C70.5 H78 Ce3 F27 N12
• Title of publication: The effects of light lanthanoid elements (La, Ce, Nd) on (Ar)CF-Ln coordination and C-F activation in N,N-dialkyl-N'-2,3,5,6-tetrafluorophenylethane-1,2-diaminate complexes.
• Authors of publication: Deacon, Glen B.; Forsyth, Craig M.; Junk, Peter C.; Kelly, Rory P.; Urbatsch, Aron; Wang, Jun
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 28
• Pages of publication: 8624 - 8634
• a: 22.712 ± 0.003 Å
• b: 22.712 ± 0.003 Å
• c: 53.514 ± 0.011 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 23906 ± 7 ų
• Cell temperature: 123 ± 1 K
• Ambient diffraction temperature: 123 ± 1 K
• Number of distinct elements: 5
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3 :H
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.1573
• Residual factor for significantly intense reflections: 0.0641
• Weighted residual factors for significantly intense reflections: 0.1438
• Weighted residual factors for all reflections included in the refinement: 0.1894
• Goodness-of-fit parameter for all reflections included in the refinement: 1.074
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No