Information card for entry 7021441

Structure parameters

• Formula: C42 H50 N2 O2 Os P2
• Calculated formula: C42 H50 N2 O2 Os P2
• SMILES: [OsH]1([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)(O)[NH2]C(C([NH2]1)(C)C)(C)C.O
• Title of publication: Structural properties of trans hydrido-hydroxo M(H)(OH)(NH2CMe2CMe2NH2)(PPh3)2 (M = Ru, Os) complexes and their proton exchange behaviour with water in solution.
• Authors of publication: Prokopchuk, Demyan E.; Collado, Alba; Lough, Alan J.; Morris, Robert H.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 28
• Pages of publication: 10214 - 10220
• a: 13.921 ± 0.0003 Å
• b: 15.8226 ± 0.0004 Å
• c: 16.9605 ± 0.0006 Å
• α: 90°
• β: 94.033 ± 0.0016°
• γ: 90°
• Cell volume: 3726.58 ± 0.18 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.079
• Residual factor for significantly intense reflections: 0.0428
• Weighted residual factors for significantly intense reflections: 0.0839
• Weighted residual factors for all reflections included in the refinement: 0.0974
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No